A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
_Sesquioxide of Antimony_ (Sb^{2}O^{3}).--In the pure state this oxide
is a white powder, is fusible at a dull red heat to a yellow liquid,
which, after cooling, is greyish-white and crystalline. If it is
heated excluded from the air, it can be volatilized completely; it
sublimes in bright crystals having the form of needles. It occurs
sometimes in nature as white and very bright crystals. It takes fire
when heated in the open air, and burns with a white vapor to
antimonious acid. It fuses with the ter-sulphide of antimony to a red
bead. It is distinguished from the other oxides of antimony by the
readiness with which it is reduced to the metallic state upon
charcoal, and by its easy fusibility and volatility.
The sesquioxide is the base of some salts--for instance, the tartar
emetic. It is not soluble in nitric acid, but is soluble in
hydrochloric acid. This solution becomes milky by the addition of
water. A part of the salts of the sesquioxide of antimony are
decomposed by ignition. The haloid salts are easily volatilized,
without decomposition. Its soluble neutral salts change blue litmus
paper to red, and are converted, by admixture of water, into
insoluble basic and soluble acid salts.
Antimonious acid (antimoniate of sesquioxide of antimony, Sb^{2}O^{3}
+ Sb^{2}O^{5}) is of a white color, but, when heated, of a light
yellow color, but changes to white again when cold. It is infusible
and unaltered by heat. It forms a white hydrate, and both are
insoluble in water and nitric acid. It is partly soluble in
hydrochloric acid, with the application of heat. The addition of water
causes a precipitate in this solution.
_Antimonic Acid _(Sb^{2}O^{5}).--In the pure state this acid is a
light yellow-colored powder. Its hydrate is white, and is insoluble in
water and nitric acid. It is sparingly soluble in hot concentrated
hydrochloric acid. It forms salts with every base, some of which are
insoluble, and others sparingly so. Notwithstanding that antimonic
acid is insoluble in water, it expels the carbonic acid from the
solutions of the carbonates of the alkalies. Antimonic acid and its
hydrate changes moistened blue litmus paper to red.
_Behavior of Antimony and its Oxides before the Blowpipe._
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