A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
_Metallic Antimony_ fuses easily upon charcoal. When heated to
glowing, and then removed from the flame, it continues to glow for
awhile, and produces a thick white smoke. The vapor crystallizes
gradually, and coats the assay with small crystals which iridesce like
mother of pearl (sesquioxide of antimony). It is not volatile at the
temperature of melted glass. Ignited in an open glass tube, it burns
slowly with a white vapor, which condenses upon the cool part of the
tube, and exhibits some indications of crystallization. This vapor
consists of the sesquioxide, and can be driven by heat from one place
to another, without leaving a residue. If the metallic antimony
contains sulphide of antimony, there is a corresponding portion of
antimonious acid produced, which remains as a white sublimate after
the sesquioxide is removed.
_Sesquioxide of antimony_ melts easily, and sublimes as a white vapor.
It may be prepared by precipitating and drying. When heated, it takes
fire previous to melting, glows like tinder, and is converted into
antimonious acid, which is now infusible. When heated upon charcoal in
the flame of reduction, it is reduced to the metallic state, and
partly volatilized. A white vapor sublimates upon the charcoal, while
the external flame exhibits a greenish-blue color. Antimonious acid is
infusible, produces a strong light, and is diminished in volume when
heated in the external flame, during which time a dense white vapor
sublimes upon the charcoal. It is not, however, in this manner reduced
to the metallic state like the sesquioxide.
_Antimonic acid_, when first heated, becomes white, and is converted
into antimonious acid. Hydrated antimonic acid, which is originally
white, appears at first yellow while giving off water, and then
becomes white again, while oxygen is expelled, and it is converted
into antimonious acid.
The oxides of antimony produce, with blowpipe reagents, the following
reactions: borax dissolves oxides of antimony in the oxidation flame
in considerable quantity to a clear bead, which is yellow while hot,
but colorless when cold. If the bead is saturated, a part of the oxide
is volatilized as a white vapor. Upon charcoal, in the oxidation
flame, it is completely volatilized, and the charcoal is covered with
a white sublimate. Heated upon charcoal in the reducing flame, the
bead is of a greyish color, and partially, if not wholly opaque, from
the presence of reduced metallic particles. A continued heat will
volatilize them, and the bead becomes clear. The addition of tin
promotes the reduction.
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