A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
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A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Saltpetre, when properly refined, does not contain any foreign salts,
and its purity may be known by a variety of experiments, as follows:
make a solution of the salt in distilled water, and filter it through
paper. Put a portion of it in a wine glass, and add a solution of
carbonate of potassa. To another portion, add a small quantity of
muriate, or in preference, nitrate of barytes. To a third portion,
add nitrate of silver. If the fluid in the first glass remains clear,
without any turbidness, we are to infer the non-existence of earthy
salts; if turbid, that it contains lime, or some other earth, either
in the form of a nitrate or muriate. The addition of oxalate of
potassa to another portion of the solution will show the presence
of lime by forming a precipitate, and the addition of carbonate of
ammonia, and then of phosphate of soda, will indicate magnesia. If
the second glass remains transparent, it shows that neither sulphuric
acid, nor any of the sulphates are present. If the fluid in the third
glass continues also clear, we infer that none of the muriates exist.
These experiments are sufficient to show the purity of saltpetre. It
would afford perhaps more satisfaction to institute also the same
experiments on other samples of nitre, by which a comparison may
be formed of the relative purity of each. To make an analysis of
the salt, with the view to determine the proportion of the foreign
substances would be altogether unnecessary for common purposes. A
regularly defined crystal would, in a great measure, point out its
purity. The double refined saltpetre is chemically pure. Artificers
determine the purity of nitre by its flame; if white, they call it
pure, if yellow, impure.
The same reagents may be used in the examination of gunpowder, as
we shall notice hereafter. If a portion of powder be mixed with
distilled water, the water will dissolve only the saline substances,
leaving the charcoal and sulphur. When the whole is thrown on a
filter, the fluid, which passes through, will contain the saltpetre,
and foreign salts, if any are present. The same experiments may
then be performed with the solution, and the quality of the nitre,
of which the gunpowder was made, be determined. Some gunpowder
absorbs a large portion of water, which is owing to the presence of
deliquescent salts. These salts may be detected by proceeding in the
way we have pointed out. The art of refining saltpetre is so well
known of late in the United States, especially by the Messrs. Dupont
of Brandywine, Delaware, that our gunpowder is of a very superior
quality. I have examined various specimens of this saltpetre, and
gunpowder made with it, and could not detect any of the sulphates
or muriates, either alkaline or earthy. For the manufacture of
gunpowder, and fire-works generally, the nitre, it may be observed,
cannot be too pure.
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