A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
In pyrotechny, it is necessary to have the nitre in powder.
Pulverizing it in a mortar is a tedious method, if a large quantity
is required for use. There is an advantage, likewise, in the mode
we will describe; because the saltpetre, besides being extremely
fine, is made perfectly dry. Put into a copper kettle, whose bottom
must be spherical, fourteen pounds of refined saltpetre, with two
quarts or five pints of water. Put the kettle on a slow fire, and if
any impurities rise and form a scum, remove them; keep constantly
stirring with two large spatulas, till the water evaporates, and
the nitre is reduced to a powder. This will be perfectly white, and
almost impalpable. If it should boil too fast, remove the kettle, and
set it on wet sand, which will also prevent the nitre from adhering
to the pot. It should be kept in a dry place. This process of
powdering saltpetre is performed on a large scale for the manufacture
of gunpowder.
_Sec. II. Of Nitrate of Soda._
This salt has been recommended in lieu of nitre, for preparing
certain fire-works; but we confess, we can see no particular
advantage in using it. It has the property of attracting humidity
from the air, and on that account is rendered unfit for the
manufacture of gunpowder. This salt is composed of nitric acid and
soda. It was formerly called _cubic nitre_. It may be formed, very
readily, by saturating nitric acid with soda, and evaporating the
solution. It crystallizes in rhomboidal prisms. It may be formed more
economically, by mixing together the solutions of nitrate of lime and
sulphate of soda, filtering the mixture, and evaporating the filtered
liquor. It will be sufficient to observe, that it deliquesces, or
absorbs moisture, and in the fire, that its phenomena are the same as
those of nitre. It does not melt so readily.
Used in the same proportion as nitre, it will form a gunpowder, which
soon, however, spoils by exposure. It will, like nitre, communicate
a yellow colour to the flame of alcohol. Experiments were made with
this salt, with the view to the fabrication of gunpowder, by MM.
Bottée and Riffault. Their conclusions, as we have stated, may be
seen in their work on _gunpowder_. Professor Proust says, that five
parts of nitrate of soda, with one of charcoal, and one of sulphur,
will burn three times as long as common powder, so as to form an
economical composition for fire-works.
The _cubic nitre_, and the _nitrum flammans_ were known, and so
called, by the older chemists. The former we have seen, is the
nitrate of soda, and the latter, is a combination of nitric acid and
ammonia. Nitrate of soda, consists of 6.75 acid + 3.95 soda.
Nitrate of ammonia possesses the property of exploding; and, when
exposed to a temperature of about six hundred degrees, is decomposed,
furnishing the nitrous oxide, called also the protoxide of azote, and
exhilarating gas, besides water. Nitrate of ammonia is composed of
6.75 acid + 2.13 ammonia + 1.125 water.
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