A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
In the manufacture of powder, particular kinds of wood are selected
for carbonization. These are generally, willow, hazle, maple, poplar,
linden, buckthorn, or alder, or those which are tender and light,
because, as they are less dense, and consequently more friable,
they enflame and consume more rapidly: they are known in the arts
by the name of _white wood_. When a less sudden effect is to be
produced with the gunpowder, and the combustion prolonged, as in some
sky-rockets, the charcoal of hard wood is to be preferred, such as
the oak, beech, &c. When the wood is gathered, the bark is removed,
and the wood exposed to the sun to dry: it is then cut into billets,
and charred. The ashes, if any be formed, are to be carefully
separated.
In considering the use of charcoal, therefore, for the preparation
of gunpowder, we are to direct our inquiries to the choice of wood
for carbonization, and the best process for carbonizing it. All light
woods, we remarked, as the linden, willow, poplar, &c. furnish the
lightest coal, and on that account are preferred. It is remarked,
that tender wood, besides making a light, friable, and porous coal,
is more combustible than ordinary hard, and more compact wood, and
the coal that it furnishes leaves less residue after combustion.
Many experiments have been made with coal prepared from different
kinds of wood, with a view of ascertaining the kind best adapted
for the manufacture of gunpowder. M. Letort, at the powder mills
of Essonne, in France, instituted a number of experiments of this
kind. He made gunpowder with the coal of several kinds of wood, and
compared its effects by a mortar eprouvette. The result was, that
the powder made with the coal of poplar, was the strongest; and the
other powder, made with the coal of the linden, willow, &c. was of
the same quality throughout. As to the second inquiry, it is hardly
necessary to repeat, that for the complete and thorough carbonization
of the wood, to produce at the same time coal of a uniform quality,
the process of charring in iron cylinders or close vessels, is to
be preferred. The point to be attended to is, to bring the wood to
a complete state of ignition, and consequently to disengage all the
volatile or fluid parts. When the gas (carburetted hydrogen) ceases
to appear, it is a criterion that the operation is finished. This
gas, it is to be recollected, will come over even after the whole
of the wood is completely ignited. The first volatile product is
the pyroacetic acid. Some saturate the acid liquor with chalk, and
decompose the acetate of lime with sulphate of soda, and separate the
acetic acid from the acetate of soda by distillation with sulphuric
acid. The acetic acid is then tolerably pure, and may be diluted for
use.
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