A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
The products of combustion may be fixed or gaseous, and either
alkalies, oxides, or acids; or, when chlorine is the supporter,
chlorides, &c. A few examples will be sufficient. By the combustion
of metals, iron for instance, we obtain a fixed product, and in
the present case an oxide of iron; by the combustion of antimony
and arsenic, the antimonic and arsenic acids; by the combustion
of charcoal, we have carbonic acid gas, a gaseous product; by
the combustion of potassium or sodium, we obtain a fixed alkali,
depending however on the quantity of oxygen; by the combustion of
sulphur, phosphorus, &c. acids; and when metals are burnt in chlorine
gas, chlorides are produced.
It is evident from facts, that, whatever theory may be assumed,
combustion occasions the production of _free_ caloric, or changes
the _condition_ of caloric, from quiescent to distributable heat.
The conclusions drawn by Mr. Davy and others, appear to have been
predicated on the absorption of the base, and development of caloric,
as in oxygen gas, and the peculiar alteration in bodies implying a
decrease in their capacity; and hence, as regards the products of
combustion, they must necessarily possess a less capacity for heat
than the mean capacity of their constituents.
Whether we regard heat as latent, in the acceptation of the term, as
applied or used by Dr. Black, or quiescent, or in a state of rest, it
is certainly evident, that combustion is a chemical change, and by it
caloric passes from a combined to an uncombined state, and is thus
made sensible, free, or thermometrical heat. Combustion may, as it
certainly does, put quiescent heat in a distributable state; but this
quiescent heat is the same in the present case, of which there can
be no doubt, as latent caloric. The thermometer will only indicate
as much caloric in the air as is in a distributable, or free state;
but, if the same air be employed to supply, or support combustion,
the heat, rendered appreciable by the senses and the thermometer,
will be in the ratio of the decomposition of the oxygen gas of the
atmosphere, and, of course, to the development of free caloric.
Public-domain text, read in full here on John Shaqi.
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