A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Berthollet's fulminating silver, which he discovered in 1788, is
another preparation, which fulminates powerfully. It is prepared by
precipitating nitrate of silver by lime-water. The precipitate is
placed on filtering paper, which absorbs the water, and the nitrate
of lime. Pure caustic ammonia is then added, which produces an effect
somewhat similar to that attending the slaking of lime. The ammonia
dissolves only a part of this precipitate. It is left at rest for ten
or twelve hours, and at the expiration of this time, there is formed,
on the surface, a shining pellicle, which is re-dissolved with a
new portion of ammonia, but which does not appear, if a sufficient
quantity of ammonia has been added at the first. The liquid is then
separated, and the black precipitate, found at the bottom, is put, in
small quantities, on separate papers. This powder explodes even when
moist, if struck with a hard body. When dry, the slightest friction
will explode it. Its detonation is owing to the same cause as that
producing the explosion of the other preparation of this metal, as it
is also composed of oxide of silver and ammonia.
The fulminating silver of Chenevix explodes only by a slight
friction in contact with combustible substances. It is nothing more
than chlorate of silver. It is formed by passing chlorine gas through
alumina, diffused in water, and afterwards digesting, in the liquor,
some phosphate of silver. The whole is to be evaporated slowly. A
single grain of this powder, with three grains of sulphur, will
explode by the slightest friction.
For the preparation of fulminating silver, the formula given
by professor Silliman of Yale College, appears to possess some
advantages. To an ounce of alcohol and as much nitric acid, he adds
100 grains of pulverized lunar caustic. A gentle heat is applied to
excite the action between them, which must be removed, the moment
they begin to act. When a thick white precipitate appears, cold water
must be added to check the action. The precipitate is then to be
collected, washed, and carefully dried. A grain or two will explode
over a candle.
_Sect. XXVII. Of Fulminating Gold._
The preparation, called by some aurate of ammonia, is formed by
dissolving gold in nitromuriatic acid, diluting the solution with
water, and adding gradually liquid ammonia, until the precipitation
ceases. The precipitate is then to be caught on a filter, well
washed with water, and dried in the air. The fulminating gold,
thus produced, exceeds the weight of the original gold employed by
thirty-three per cent.
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