A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Three or four grains of this powder, heated on a knife, will explode
with a loud report. The temperature required for its explosion
is between 230° and 300°. Ten or twelve grains will penetrate a
copper-plate, of the thickness of a playing card. The facility with
which this powder explodes, is increased by drying. If it be heated
until it becomes black, the slightest touch will cause a detonation.
This powder is composed of oxide of gold, ammonia, and a portion of
chlorine; and, during its detonation, water, nitrogen and chlorine
are evolved, the gold being revived.
The presence of ammonia is necessary to give to gold the property of
fulminating. Fulminating gold accordingly loses this property, the
moment the ammonia is separated. Concentrated sulphuric acid, melted
sulphur, fat oils, and ether have this effect.
The discoverer of fulminating gold was a German Benedictine Monk,
who lived about the year 1413. Basil Valentine has described the
preparation of it very accurately. He recommends, however, mixing
sal ammoniac with aqua fortis, the old mode of making aqua regia,
and distilling the mixture; then putting in the gold in leaf. After
the acid is saturated, he adds _oleum tartari_, or _sal tartari_
(carbonate of potassa) dissolved in water; and the precipitated
_calx_, thus obtained, when collected, washed, and dried in the
open air, will fulminate. In this process, it is evident, that the
aqua regia, prepared with sal ammoniac, contains ammonia, and, when
the gold is dissolved, and the potash added, the oxide of gold
separates, and, from the composition of the powder, must combine with
a portion of ammonia, and hence produce fulminating gold. He remarks,
that distilled vinegar digested on fulminating gold, destroys its
fulminating properties, and observes also, that care must be taken to
prevent its explosion. He also knew that sulphur would have the same
effect.
Bergman (_Treatise on Pulvis Fulminans_) describes the process
employed by Valentine; and Beckman (_History of Inventions_, v. iii.
p. 132,) observes, that, after the time of Valentine, Crollius, who
lived in the last half of the 16th century, was well acquainted with
fulminating gold, and made its preparation more generally known.
In the _Oswaldi Crollii Basilica Chymica_, 4to, p. 211, published
at Frankfort, in 1609, the process is also to be found. He calls
it _aurum volatile_, and speaks of its being useful in medicine.
Beguin, however, appears to have given it the appellation of _aurum
fulminans_, if we judge from his _Tyrocinium Chymicum_, 12mo, printed
in 1608.
_Sect. XXVIII. Of Fulminating Platinum._
Public-domain text, read in full here on John Shaqi.
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