A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Iodine is a particular substance, which has the property not only
of combining with oxygen and hydrogen, forming iodic and hydriodic
acid, but also with various bases constituting a class of bodies,
called iodides. Its union with azote produces a singular substance,
which detonates with great violence, when slightly touched or heated.
It may be formed, by putting a quantity of iodine into the water of
ammonia. It will be gradually converted into a brownish-black matter,
which is the iodide of azote. It is formed in this process by the
iodine, in the first instance, decomposing a part of the ammonia; the
hydrogen of which combines with a portion of the iodine, and produces
hydriodic acid, which then unites with the undecomposed part of the
ammonia, and forms the hydriodate of ammonia; whilst the azote the
other constituent of the ammonia, unites with another portion of the
iodine, and forms the compound in question.
When exposed to the air, iodide of azote gradually flies off in
vapour, without leaving any residue. The products of its detonation
are iodine and azotic gas.
The iodide of azote was discovered by M. Courtois, and subsequently
examined by M. Colin. Iodine, brought in contact with ammoniacal gas,
a combination taking place, produces a viscid shining liquid of a
brownish-black colour, which, as the saturation goes on, loses its
lustre.
This liquid does not detonate, and is considered to be an iodide of
ammonia; but, when it is added to water, it is decomposed, as well as
the water, and we obtain two new compounds, as before observed, the
hydriodate of ammonia, and iodide of azote. This iodide detonates.
Hence it is evident, that hydrogen united with azote, in ammonia,
prevents explosion; for the moment it is taken away, by the formation
of hydriodic acid, and the azote itself combines with the iodine,
a fulminating compound is formed. The elements of this powder are
feebly united.
It is found, that hydriodate of ammonia has the property of
dissolving a large quantity of iodine, and, if suffered to remain
with the iodide of azote, of decomposing it also, and setting the
azote at liberty. Water is said to have the same effect, although
feebly.
Iodate of potassa, a salt composed of iodic acid and potassa, when
mixed with sulphur, and struck with a hammer, will detonate, in
consequence of the decomposition of the iodic acid. The iodate
of potassa may be formed very readily by agitating iodine with
a solution of caustic potassa. The water is decomposed, and the
hydriodate of potassa is also formed, which, being very soluble,
remains in solution, whilst the iodate separates, on concentrating
the liquor, and suffering it to stand.
Chlorate, as well as nitrate of silver, form with sulphur fulminating
powders.
Iodic acid, called also oxy-iodine, (prepared by exposing iodine to
the action of euchlorine,) when heated in contact with inflammable
substances, and the more combustible metals, will produce detonations.
Public-domain text, read in full here on John Shaqi.
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