A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
It appears, however, that sulphur has a stronger affinity for oxygen
than iodine has, and iodine a stronger affinity than chlorine for
the same element. Hence chloric acid is more readily decomposed
by inflammable bodies than iodic acid, and iodic acid, sooner than
sulphuric acid.
The acids, which chlorine, iodine, and sulphur form respectively
with oxygen, Gay-Lussac remarks, have their elements more strongly
_condensed_, than the same substances united with hydrogen.
_Sect. XXXI. Of Detonating Oil, or Chloride of Azote._
This oil is produced by the action of chlorine on ammonia, by using
some of the salts of this alkali. A small jar of chlorine gas is
transferred into a basin, containing a solution of nitrate or muriate
of ammonia, a little heated: an absorption will gradually take
place, and the gas be condensed. An _oily film_ will now appear on
the surface of the ammoniacal solution, which, as it increases, will
form globules and fall through the liquor. This substance is the
detonating oil, composed, according to analysis, of chlorine, azote,
and hydrogen. It is supposed by Messrs. Wilson, Porret, and Kirk,
that the hydrogen serves as a medium of union between the chlorine
and azote, and that, in detonation, the powerful effect is owing to
the chlorine.
Detonating oil explodes violently at 212 degrees; and even when
touched with cold inflammable substances, as a portion of olive oil,
about the size of a pin's head, the detonation is also violent, and
the vessel, in which the experiment is made, will, in most cases, be
broken into fragments.
Detonating oil is considered, however, a chloride of azote. In order
to prevent the decomposition of the chloride by the ammoniacal salt,
a thin stratum of muriate of soda, put into the bottom of the vessel,
is recommended. Its specific gravity is 1.653. Warm water, put into
a vessel containing it, will change it to an aeriform fluid of an
orange colour. "I attempted," says Sir H. Davy, "to collect the
products of the new substances, by applying the heat of a spirit-lamp
to a globule of it, confined in a curved glass tube over water: a
little gas was at first extricated; but, long before the water had
attained the temperature of ebullition, a violent flash of light was
perceived, with a sharp report; the tube and glass were broken into
small fragments, and I received a severe wound in the transparent
cornea of the eye, which has produced a considerable inflammation of
the eye, and obliges me to make this communication by an amanuensis.
This experiment proves what _extreme_ caution is necessary in
operating on this substance; for the quantity I used was scarcely as
large as a grain of mustard seed." _Phil. Trans._ 1813, Part I.
Public-domain text, read in full here on John Shaqi.
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