A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
In _vacuo_, it expands into vapour, which still possesses the power
of exploding by heat. In water, it gradually disappears, the water
becoming acid, and azote being evolved. Mercury decomposes it, and a
white powder (calomel) is formed, while the azote is set at liberty.
Dr. Ure (_Chemical Dictionary_, Art. _Nitrogen_,) observes, that the
mechanical force of this compound, seems superior to that of any
other known substance, not even excepting the ammoniacal fulminating
silver. The velocity of its action appears to be likewise greater.
The Doctor touched a minute globule of it, in a platina spoon,
resting on a table, with a fragment of phosphorus at the point of a
pen-knife, and the blade was instantly shivered into fragments by the
explosion.
Messrs. Porret, Wilson, and Kirk (_Nicholson's Journal_, Vol. XXXIV,)
employed 125 different substances, by bringing them in contact; and
out of that number the following caused it to explode:
Supersulphuretted hydrogen,
Phosphorus,
Phosphuret of lime,
Phosphuretted camphor,
Camphoretted oil,
Phosphuretted hydrogen gas,
Caoutchouc,
Myrrh,
Palm oil,
Ambergris,
Whale oil,
Linseed oil,
Aqueous ammonia,
Olive oil,
Sulphuretted oil,
Oil of Turpentine,
---- Tar,
---- Amber,
---- Petroleum,
---- Orange peel,
Naphtha,
Soap of silver,
---- Mercury,
---- Copper,
---- Lead,
---- Manganese,
Fused Potassa,
Nitrous gas.
See _Detonating Works_.
According to Mr. Davy, chloride of azote contains
4 vols. of chlorine = 10 + } or { 4 primes = 18.0 +
1 ---- azote = 0.9722 } { 1 ---- = 1.75,
or very nearly 10 by weight of chlorine to 1 of azote.
_Sect. XXXII. Of Pyrophorus._
Pyrophorus is a black substance, which takes fire spontaneously, when
brought into contact with air. It is the luft-zunder, or air-tinder
of the Germans. It first emits sulphuretted hydrogen gas, and in a
few seconds becomes red-hot, burning with a bluish flame. Pyrophorus
consists of alumina, charcoal, and sulphuret of potassa, and also,
according to some, of potassium, which is alleged to be formed in its
preparation. Be this as it may, it seems, that water is decomposed in
its combustion, that sulphuretted hydrogen gas is emitted, which is
inflamed by the oxygen gas of the atmosphere, and that, during the
combination of oxygen, a degree of heat is produced, which causes
the ignition of the charcoal, as well as the inflammation of the
remaining sulphur.
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