A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
This preparation of copper is used in some fire-works. It
communicates a green colour to flame. When combined with carbonaceous
substances, the combustion is vivid. This is owing to the
decomposition of the nitric acid, (in the same manner as the acid of
nitrate of potassa and other nitrates is decomposed), during which
carbonic acid and deutoxide of azote are produced. Nitrate of copper
has been more particularly recommended for the preparation of match
stick, similar to that of M. Cadet, and of match rope. It is used in
the same manner as the nitrate of lead. M. Proust used it in lieu of
nitrate of lead when repeating some experiments of M. Born. It is
more expensive than the acetate, or even the nitrate of lead. Its
effect, however, is the same.
Nitrate of copper attracts the moisture of the atmosphere, and
deliquesces. Acetate of lead, on the contrary, by exposure to the air
gradually effloresces, and in time is decomposed. The preparations of
lead, for that reason, are preferable to the nitrate of copper.
Nitrate of copper is formed by dissolving copper in nitric acid; and,
when the acid is saturated, the requisite quantity of water may be
added. The salt may be obtained in a dry state by evaporation; and,
after being dissolved in water, the wood or rope may be soaked in it.
Dry nitrate of copper, wrapped up in tin-foil, will produce no
action; but, if water be added, sufficient to moisten it, and then
the foil closed tightly, combustion will take place. The water
promotes chemical action by dissolving the nitrate of copper, which
is then decomposed by the tin, and the quantity of caloric, put in a
distributable state, is sufficient to inflame the tin. The details of
the rationale will be given hereafter.
The ammonia-nitrate of copper is fulminating copper. The chlorate of
copper is a deflagrating salt. Ammonia added to nitrate of copper,
first separates an oxide, and then dissolves it. It is more than
probable, that nitrate of ammonia causes the ammonia-nitrate to
explode.
_Sec. LVIII. Of Strontia._
The earth called strontia or strontian, is found abundantly in
different parts of the world, in combination with carbonic and
sulphuric acids. The carbonate of strontia or strontianite,
effervesces with acids, and burns with a purple flame. It contains
about 60 or 70 per cent. of earth. The sulphate of strontia, or
celestine, contains about 57 of strontia.
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