A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
When carbonate of strontia is mixed with charcoal powder, and exposed
to a heat of 140° of Wedgwood's pyrometer, the carbonic acid will
be expelled, and pure strontia remain. The earth may be obtained
in a pure state, by dissolving the carbonate in nitric acid, and
evaporating the solution until it crystallizes, and exposing the
crystals, in a crucible, to a red heat, until the nitric acid is
driven off. If the carbonate cannot be had, the sulphate may be
employed. For this purpose, it is to be pulverized and mixed with
an equal weight of carbonate of potassa, and boiled in water. The
carbonate of strontia, thus obtained, which exists in the form of a
powder, is to be treated with nitric acid as already described.
Strontia, like the other earths, is a compound body, having a
metallic basis, called _strontium_, which, united with oxygen, forms
the earth.
The specific gravity of strontia approaches that of barytes. Like
pure barytes, it is soluble in water, forming strontia water. It
requires rather more than 160 parts of water at 60° to dissolve it;
but much less of boiling water.
The solution of strontia in water, when evaporated, will crystallize
in thin, transparent, quadrangular plates, generally parallelograms,
seldom exceeding a quarter of an inch in length. These crystals
contain about 68 per cent. of water; and are soluble in little
more than twice their weight of boiling water, and in 54.4 times
their weight of water at 60°. When dissolved in alcohol, they give
a blood-red colour to its flame. The solution of strontia changes
vegetable blues to green. Strontia differs from barytes in being
infusible, much less soluble, of a different form, weaker in its
affinities, and not poisonous.
The metallic base of strontia, which was discovered by Sir H. Davy,
in 1808, when exposed to the air, or when thrown into water, rapidly
absorbs oxygen, and is converted into strontia.
As strontia communicates a red colour to flame, it has been used in
certain compositions of artificial fire. The brilliant red fire,
sometimes used in theatres, owes its colour to this earth. See
_Theatrical fire-works_. Muriate and nitrate of strontia will give a
red or purple colour to the flame of alcohol. See _coloured flame of
alcohol_.
If a piece of cloth be dipped in a solution of muriate, nitrate,
or acetate of strontia, or in strontia water, and then immersed in
alcohol, it will burn with a red flame.
M. Fourcroy, (_Système des Connaissances Chimiques, &c._ tome iii,)
mentions the use of nitrate and muriate of strontia, in artificial
fire-works, for the purpose of communicating a red colour to the
flame of combustible bodies. Since that time, the nitrate, in
particular, has been recommended and used.
One of the characters of the salts of strontia, is, that they give a
red flame to burning bodies; whereas the salts of barytes or of lime,
used in the same manner, communicate a yellow flame.
Public-domain text, read in full here on John Shaqi.
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