A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Boracic acid forms two salts with soda; the borate, properly so
called, and borax. It is supposed to be our borax, that Pliny
mentions under the name _crysocolla_, so called by the ancients.
Others, however, assert, that their crysocolla was nothing more than
the rust of copper, triturated with urine. The impure borax in the
East Indies, is called _tincal_. When borax is melted, and exposed
for some time to heat, it loses its water, and is changed into what
is known by the name of _calcined borax_.
The easiest process for obtaining boracic acid is to make a
concentrated solution of borax in hot water, and add by degrees,
sulphuric acid, which will unite with the soda; and, as the fluid
cools, the boracic acid will separate in shining laminated crystals.
No more acid should be added than is sufficient to make the solution
slightly sour. The crystals are to be washed with cold water, and
drained upon brown paper.
One of the principal characters of boracic acid is, that it is very
soluble in alcohol, to the flame of which it communicates a green
colour. Paper dipped in this solution, burns in the same manner.
In consequence of this property of imparting a green colour to
flame, I made some experiments with it, for the purpose of preparing
_green fire_; and found, that, by employing it in the proportion of
one-eighth, the flame was always green, provided that the flame of
the combustible used, was not tinged of any other colour. Nitre,
charcoal, and boracic acid will give a green; also nitre, lamp oil,
and boracic acid; nitre, alcohol, and boracic acid, along with
charcoal; and chlorate of potassa, charcoal, and boracic acid, with
or without the addition of alcohol. But, although boracic acid
communicates a lively green, its expense will prevent its use in that
way, especially as many other preparations, as those of copper, will
have the same effect, and are more economical on account of their
price. See the _Coloured Flame of Alcohol, and Coloured Fire_.
Oils, when assisted by heat, will dissolve boracic acid. In naphtha,
it is very soluble. With oils, it yields fluid and solid products,
which give a green colour to the flame of alcohol. It is not a
combustible acid, but only imparts colour to the flame of combustible
bodies.
Boron will unite with fluorine, the radical of fluoric acid. When
one part of vitrified boracic acid, two of fluate of lime or fluor
spar, and twelve of sulphuric acid are distilled, an acid gas will be
obtained, called fluo-boric gas. For the properties of boron, consult
Thenard's _Traité de Chimie_.
PART II.
INSTRUMENTS, TOOLS, AND UTENSILS.
CHAPTER I.
OF THE LABORATORY.
Public-domain text, read in full here on John Shaqi.
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