A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
The saline combinations of strontia were examined with particular
attention by Dr. Hope. See _Edinburg Philosoph. Transactions_ for
1790.
Nitrate of strontia may be formed by dissolving carbonate of
strontia, or the sulphuret obtained by decomposing the sulphate by
charcoal, in nitric acid, filtering the solution, evaporating it, and
suffering it to crystallize.
Nitrate of strontia deflagrates on ignited coals. Dr. Hope pointed
out, that if nitrate of strontia be exposed to a red heat, and a
combustible substance be, at this time, brought in contact with
it, a deflagration, with a very vivid red flame, will be produced.
When a crystal of this salt is put into the wick of a candle, it
communicates a beautiful purple flame. It does not deliquesce in the
air, and, therefore, the compositions, into which it enters, cannot
spoil on that account. Nicholson (_Chemical Dictionary_,) observes,
that nitrate of strontia may be used in the art of pyrotechny.
For this purpose, however, it is mixed with sulphur, chlorate of
potassa, and sulphuret of antimony; and sometimes with the addition
of sulphuret of arsenic and charcoal, as in the _red fire_ for
theatrical uses.
The muriate of strontia has similar properties. Davy first observed,
that when strontia was heated in chlorine gas, it gave out oxygen
gas, and a chloride of strontium was formed.
Muriate of strontia is formed very readily, by dissolving the
carbonate or sulphuret of strontia in muriatic acid, and evaporating
the solution in order to obtain crystals. These crystals are very
soluble in water. They are soluble, also, in twenty-four times their
weight of pure alcohol, at the temperature of 60°. This alcoholic
solution, we remarked, burns with a fine purple colour. These
crystals suffer no change when exposed to the air, except they be
very moist; in which case, they deliquesce. When heated, they first
undergo the watery fusion, and are then reduced to a white powder.
Fourcroy recommends the muriate of strontia for fire-works.
Carbonate of strontia, when thrown in powder on burning coals,
produces red sparks.
Acetate of strontia, another salt used in fire-works, is formed
by dissolving strontia, or its carbonate, in acetic acid. It will
crystallize. The crystals are not affected by exposure to the air.
When heated, its acid is decomposed, as happens to all the other
acetates.
_Sec. LIX. Of Boracic Acid._
Borate of soda, or borax, is a salt, which has long been known, and
is used chiefly in the arts as a flux for the fusion of bodies, and
for soldering. Boracic acid is a compound body, consisting of a newly
discovered substance, called boron, and oxygen. Homberg obtained
the acid from borax in 1702, by distilling a mixture of borax, and
sulphate of iron. He supposed that it was a product of the latter;
and hence it was called the _volatile narcotic salt of vitriol_, or
_sedative salt_.
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