A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Again, in a composition of mealed powder, rosin and sulphur, with
or without the addition of saw dust, we infer, from the composition
of the ingredients and the chemical action which subsequently takes
place, that the products of combustion would be carbonic acid gas,
sulphurous acid gas, water, sulphuretted hydrogen, and probably
azotic, and nitric oxide gases. If the filings of steel, brass,
zinc, or copper, enter into the composition, besides the products
above-mentioned, there would be either an oxide of iron, an oxide
of zinc, or, an oxide of copper, according as one or other of these
metals are employed.
Copper, in fire-works, has the effect of communicating a green
colour to the flame. M. Homberg, (_Collection Acad._) observes, that
the green colour in such cases is owing to the _dissolution_ of
the metal, which in fact is nothing more than the _effect_ of its
oxidizement.
The various compositions for brilliant fire, as the Chinese fire, owe
their peculiar character to pulverised cast iron, and commonly to
steel and iron filings. Now the effects in these cases are the same;
for the same oxidizement ensues, more or less rapidly, which in fact
distinguishes the kinds of brilliant fire. That of the Chinese is the
most perfect, and next is the composition made with steel filings. It
will be seen, however, that compositions generally are governed, in
their respective appearances when inflamed, by the purity, as well as
the proportion of other substances, which enter into them; and hence
much of their effect depends on collateral circumstances, which we
purpose to consider when we treat of the compositions individually.
That the light of certain burning bodies may be increased, is evident
from these facts; and experiment has shown, that the intensity of
the light of burning sulphur, hydrogen, carbonic oxide, &c. is
increased by throwing into them, zinc, or its oxide, iron, and other
metals, or by placing in them very fine amianthus or metallic gauze.
Protochloride of copper burns with a dense red light, tinged with
green and blue towards the edges. If the hydrogen of the oil acts in
separating the chlorine from the copper, and the reduced copper is
ignited by the charcoal, this appearance must necessarily ensue.
When solid matter is the product of combustion, as in the burning
of phosphorus, zinc, iron, &c. the flame is remarked to be more
intense. Flame may be modified under other circumstances, as we will
have occasion to mention hereafter. When, for instance, a wire-gauze
safety-lamp is made to burn in a very explosive mixture of coal gas
and air, the light is very feeble and of a pale colour; but when a
current of coal gas is burnt in atmospheric air, the combustion is
rapid and the flame brilliant.
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