A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
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A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
All nitrates, as well as the different hyperoxymuriates, or
chlorates, contain oxygen as an essential ingredient in the acid of
their respective salts, which is readily given up to inflammable
substances.
When nitrates are employed for fire-works, they should be free from
moisture, or water of crystallization, unless otherwise required.
The presence of water may, in many cases, prove injurious to the
composition; and, consequently, the effect in those instances, may be
influenced by this circumstance. The composition of nitric acid, and
the action of carbon in the decomposition of the nitrates, or salts
formed by the union of nitric acid with sundry bases, will claim our
attention in the article on gun-powder.
With respect to the production of colours, some remarks on this
subject may be here added.
Speaking of colours, Haüy (_Elementary Treatise of Natural
Philosophy_, trans. ii. p. 253.) takes into view their formation
according to the Newtonian doctrine; and in a note by the translator,
several instances are given of the change of colour by oxidizement
and other processes. Iron when exposed to heat in contact with
atmospheric air gradually absorbs oxygen, and changes its colour.
The colours produced depend entirely on the quantity of oxygen, and
on the absorption of some of the rays of light, and the reflection
of others. See _Iron_. The tempering of steel instruments depends on
this property, and also the blueing of sword blades, and many similar
operations. The first impression of fire usually developes a blue
colour; a second degree produces a yellow; and, if the oxidizement
augments, the iron becomes red. The major part of the metals present
similar phenomena.
In vegetables, the blue colour is formed by fermentation; and many of
these colours are susceptible of passing to red by a greater quantity
of oxygen, as they depend on the absorption of oxygen. It is thus
that the green fecula of indigo becomes blue; turnsol, red by air and
acids; and the protoferrocyanate of iron, blue when exposed to the
air.
When meat putrefies, the first degree of oxygenation decides the blue
colour; the red soon succeeds as the process goes on. It would seem
that the maximum of oxidation determines the reflection of rays of
every kind, in the same proportions as subsist in solar light, of
which we have many instances in combustion.
The flame of burning bodies exhibits the same phenomena. It is blue
when the combination of oxygen is slow; red when it is stronger, and
white when the oxygenation is complete.
These facts lead to the conclusion, that the combination of oxygen,
and its proportions, give birth in bodies to the property of
reflecting corresponding rays of light; but, since the combination
of oxygen in different proportions ought to change the thickness
and density of the component laminæ, and, consequently, to produce
variations in the colours, this doctrine is not easily reconciled
with the received theory.
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