A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
The crude saltpetre contains about seventy-five per cent of nitrate
of potassa. The quality may be determined by treating it with a
saturated solution of pure nitrate of potassa, which cannot dissolve
any more of the nitrate, but will dissolve any foreign salts. The
twenty-five parts of the foreign substances, contained in the crude
saltpetre, are composed of a large quantity of marine salt, and of
a small portion of muriate of potassa. It is necessary to separate
them, and other foreign substances. The operation for this purpose,
is called the _refining of saltpetre_.
The refining of saltpetre is founded principally upon the property,
which nitre has, of being more soluble in warm water, than the
muriate of soda, and muriate of potassa. Thirty parts of saltpetre,
and six parts of water are put into a boiler and the liquor is
heated. By this means, there is precipitated a large quantity of
marine salt mixed with muriate of potassa. A small quantity of water
is added from time to time, to keep the nitre in solution.
When the foreign salt is not fully deposited, the liquor is
clarified, and more water is added, sufficient to form ten parts,
including that which has already been poured upon it. The liquor
is removed, when it is clear and less heated, and put into copper
vessels, where it is agitated to prevent crystallization, and to
effect the pulverization of the saltpetre.
The saltpetre obtained by this process is not sufficiently pure.
The purification is completed by washing it with water saturated
with nitre, which dissolves the foreign substances. This washing is
completed in a vessel, the bottom of which has been pierced with
holes. The nitre, however, is left some hours in contact with the
water, when the latter is permitted to run out. When the solution is
of the same degree of concentration as that of the saturated water,
the operation is finished. The nitre is dried for use.
The old process of refining saltpetre is thus described: Put into a
copper, one hundred pounds of nitre, and fourteen gallons of water;
let it boil gently half an hour, removing the scum as it forms; then
stir it, and before it settles put it into filtering bags, which must
be suspended from a rack. Put under the filters glazed earthen pans,
to receive the liquor; in which place sticks for the crystals to form
on. In two or three days, it will all crystallize.
In some saltpetre works, sulphate of potassa is used with advantage.
This salt is furnished in abundance, by the combustion of a mixture
of nitre and sulphur, in the manufacture of oil of vitriol. It
forms the residue after the combustion. It is likewise produced in
the preparation of nitric acid, in the decomposition of nitrate
of potassa, by sulphuric acid. It may, therefore, be obtained in
quantity, from the oil of vitriol manufacturers, and the aquafortis
distillers. It is usually called _vitriolated tartar_.
Public-domain text, read in full here on John Shaqi.
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