A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
It is known that sulphuric acid forms, with lime, an almost insoluble
compound, called sulphate of lime, or gypsum; and hence, when
sulphate of potassa is mixed with a solution of nitrate of lime,
nitrate of potassa is formed, which remains in solution, and sulphate
of lime is precipitated. The same effect takes place with all earthy
nitrates. For the application of sulphate of potassa, in this way, we
are indebted to M. Berard. It might be advantageously employed in
decomposing the calcareous nitrate of the nitre-caves of the western
country.
M. Longchamp has recommended the use of sulphate of soda, or
Glauber's salt, for decomposing the muriate of lime, which exists
occasionally in impure nitre. These two salts reciprocally decompose
each other; sulphate of lime is precipitated, and muriate of soda
remains in solution. The latter is separated by evaporating the
nitrous solution.
M. de Saluces (_Mémoire de l'Académie des Sciences de Turin,
Année, 1805 à 1808_,) has proposed a new process for purifying
nitre. It consists in filtering it through argillaceous earth, or
clay. Although the process is highly spoken of, yet we can see no
particular advantage it possesses.
Chaptal observes, that the process mostly in use is that of
dissolving 2000 pounds of crude saltpetre in a copper boiler, in 1600
lbs. of water. As the solution is made by the heat, the scum, which
forms, is taken off. Twelve ounces of glue, dissolved in ten pints of
boiling water, and mixed with four pails full of cold water, are then
added. This addition cools the solution. As to the manipulations of
the process, they have been given. The principal thing to be attended
to, is to separate the marine salt, which is done during the boiling.
To pass this saltpetre through a second operation, in order the
more to purify it, it is again dissolved, in the proportion of 2000
pounds, in one-fourth of its weight of water. Heat is applied. The
scum is separated; a solution of 8 ounces of glue in one or two pails
full of water is then added. After the solution becomes clear, it
is suffered to cool, and at the expiration of five days, it will
crystallize, or form in a mass, which is then exposed to the air six
or eight weeks to become completely dry.
In treating of the formation of nitre in France, Bottée and Riffault
(_Traité de l'Art de Fabriquer la Poudre à Canon_,) consider it under
the following heads:
1. _The constituent principles of nitre; its generation, and the
theories respecting it._ In this article, the composition of nitric
acid and its union with potassa, and the production of artificial
nitre, are taken into view.
2. _Nitrous earths, and substances which yield saltpetre._ This
subject comprehends a view of the substances, which contain
saltpetre, as well as those which afford it by nitrification.
3. _The preparation of the substances to produce saltpetre._ This
article relates to the manipulations required for the production of
nitre.
Public-domain text, read in full here on John Shaqi.
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