A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Ammonic Oxalate~ (Am_{2}C_{2}O_{4}.2H_{2}O) is used chiefly for the
separation of lime. The solution is made by dissolving 15 grams of the
salt in 100 c.c. of water.
~Ammonic Sulphide~ may be purchased in the state of a strong solution.
It is yellow, and contains the disulphide, S_{2}Am_{2}. It serves the
same purpose as is obtained by passing a current of sulphuretted
hydrogen through an ammoniacal solution; but has the disadvantage of
loading the solution with sulphur, which is precipitated when the
solution is subsequently acidified. It is useful for dissolving the
lower sulphide of tin (SnS).
~Baric Carbonate~ (BaCO_{3}) is sometimes used for precipitating the
weaker bases. It should be prepared when wanted by precipitating a
solution of baric chloride with ammonic carbonate and washing. The moist
precipitate is used without drying.
~Baric Chloride~, BaCl_{2}.2H_{2}O.--A crystallised salt, soluble in
2-1/2 parts of water. It is used for the detection and separation of
sulphates. Make a 10 per cent. solution.
"~Black Flux.~"--A mixture of finely divided carbon with carbonate of
potash or with carbonates of potash and soda. It is prepared by heating
tartar or "rochelle salt" until no more combustible gas is given off.
One gram will reduce about 2 grams of lead from litharge.
~Borax~, Na_{2}B_{4}O_{7}.10H_{2}O.--It is chiefly used as a flux in dry
assaying, as already described. It is also used in testing before the
blowpipe; many metallic oxides impart a characteristic colour to a bead
of borax in which they have been fused.
~Calcium Chloride.~--The crystallised salt is CaCl_{2}.6H_{2}O; dried at
200° C. it becomes CaCl_{2}.2H_{2}O, and when fused it becomes
dehydrated. The fused salt, broken into small lumps, is used for drying
gases. It combines with water, giving off much heat; and dissolves in a
little more than its own weight of water. Strong solutions may be used
in baths in which temperatures above the boiling-point of water are
required. One part of the salt and 2 of water give a solution boiling at
112°, and a solution of 2 parts of the salt in 1 of water boils at 158°.
The salt is very little used as a reagent.
~Calcium Fluoride~ or "~Fluor Spar~," CaF_{2}.--The mineral is used as a
flux in dry assaying; it renders slags which are thick from the presence
of phosphates, &c., very fluid. Mixed with hydrochloric acid it may
sometimes be used instead of hydrofluoric acid.
~Calcium Carbonate~, CaCO_{3}.--It is precipitated in a pure state by
ammonic carbonate from a solution of calcium chloride. It is used for
standardising. In the impure state, as marble or limestone, it is used
in the preparation of carbonic acid.
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