A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Calcium Hydrate~ or ~"Lime Water."~--This is used in testing for carbon
dioxide and in estimating the amount of that gas present in air. It may
be made by slaking quicklime and digesting the slaked lime with water.
One hundred c.c. of water at 15° C. dissolves 0.1368 grams of the
hydrate (CaH_{2}O_{2}), and hot water dissolves still less. "_Milk of
lime_" is slaked lime suspended in water.
~Cobalt Nitrate~ (Co(NO_{3})_{2}.6H_{2}O) is used in a 10 per cent.
solution for the detection of oxides of zinc, aluminium, &c.; on
ignition with which it forms characteristically coloured compounds.
~Copper~, Cu.--Pure copper, as obtained by electrolysis, can be
purchased. This only should be used.
~Copper Oxide~, CuO.--It occurs as a black, heavy, and gritty power, and
is used for the oxidation of carbon and hydrogen in organic substances.
It should be ignited and cooled out of contact with air just before
using, since it is hygroscopic. Oxide of copper which has been used may
be again utilised after calcination.
~Copper Sulphate~ (CuSO_{4}.5H_{2}O) contains 25.4 per cent. of copper.
It is used in the outer cell of a Daniell-battery. The commercial salt
is used for this purpose. The re-crystallised and pure salt is used for
preparing the anhydrous sulphate, which is used for detecting moisture
in gases. For this purpose it is dried at 200° C. till no trace of
green or blue colour remains. It must be prepared when wanted. It may be
conveniently used in the form of pumice-stone, saturated with a solution
of the salt and dried. Traces of moisture develop a green colour.
~Ferric Chloride~, Fe_{2}Cl_{6}. (When crystallised,
Fe_{2}Cl_{6}.6H_{2}O.)--The solution is prepared as described under
iron. The commercial salt contains arsenic, and, since the chief use of
ferric chloride is for the determination of this substance, it must be
purified (_see_ under ARSENIC).
~Ferric Sulphate~ (Fe_{2}(SO_{4})_{3}) is a yellowish white deliquescent
salt. It is used as an indicator in volumetric silver assaying, and for
the separation of iodine from bromine. It may be purchased as iron alum,
Am_{2}Fe_{2}(SO_{4})_{4}.24H_{2}O. But it is best prepared by adding
strong sulphuric acid to ferric hydrate in equivalent proportions. Use
it as a solution containing 2 or 3 per cent. of iron.
~Ferrous Sulphate~, FeSO_{4}.7H_{2}O.--The granulated form is best, and
can be purchased pure. It is used for standardising. It keeps better in
crystals than in solution. It is readily soluble in water, but the
solution is best made with the help of a little free acid. As a re-agent
use a 10 per cent. solution. The crystals should be clear bluish-green;
if their colour is dark green, brown, or blue, they should be rejected.
~Ferrous Sulphide~ (FeS) is used for the preparation of sulphuretted
hydrogen. It may be purchased and broken in small lumps, nut-size, for
use.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account