A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Lead Dioxide~ (PbO_{2}) occurs as a dark-brown powder. It is used as an
oxidizing agent and for absorbing sulphurous oxide. It can be prepared
by digesting red lead with warm dilute nitric acid; washing and drying
the residue.
"~Litharge~," PbO.--It can be purchased as a yellow heavy powder. It is
used in dry assaying as a flux, as a desulphurising agent, and also as a
source of lead. It always contains some silver, the amount of which must
be determined.
~Litmus.~--This is an organic colouring matter which is turned red by
acids and blue by alkalies. For ordinary purposes it is best used as
litmus paper, which may be purchased in small books. A solution is
prepared by digesting 15 or 20 grams of the commercial litmus in 100
c.c. of water on the water bath. After being allowed to settle, it is
filtered and made just faintly red with acetic acid. Then there is
added a drop or two of a solution of soda and 10 c.c. of alcohol. It
should be kept in a loosely-covered bottle.
~Magnesia~, MgO.--It may be purchased as "calcined magnesia." It is used
for making "magnesia mixture," and should be kept in a corked
wide-mouthed bottle.
"~Magnesia Mixture.~"--Dissolve 22 grams of magnesia in about a quarter
of a litre of dilute hydrochloric acid, avoiding excess. Add 5 grams of
magnesia, boil, and filter. Add 300 grams of ammonic chloride, and 250
c.c. of strong ammonia; and dilute with water to 2 litres. It should be
kept in a stoppered winchester.
~Magnesium Sulphate~, MgSO_{4}.7H_{2}O.--It can be purchased very pure,
and is occasionally used as a standard salt.
~Manganese Dioxide~, MnO_{2}.--It is used in the preparation of
chlorine. The commercial article is not pure, but is sufficiently so for
this purpose.
~Marble~, CaCO_{3}.--Fragments of the white crystalline variety only
should be used. It is used as a source of lime and of carbon dioxide.
~Mercury~, Hg.--This can be purchased pure. It should have a bright
surface, flow without a tail, and leave no residue on ignition. It is
used as a standard; for amalgamation; and as a confining liquid in gas
analysis.
~Mercuric Chloride~ (HgCl_{2}) may be purchased pure. Make a 5 per cent.
solution in water. It is used for destroying an excess of stannous
chloride; for removing sulphuretted hydrogen from solution; and as a
test for stannous salts.
~Microcosmic Salt~, HAmNaPO_{4}.8H_{2}O.--When fused NaPO_{3} is formed.
It is used in testing for metallic oxides and silica before the
blowpipe. The crystals are sometimes used as a standard for phosphoric
acid.
"~Nessler's Solution.~"--Mode of preparation: Dissolve 35 grams of
potassium iodide in 100 c.c. of water; dissolve 17 grams of mercuric
chloride in 300 c.c. of water, and pour this solution into that of the
iodide till a permanent precipitate is produced; make up to 1 litre with
a 20 per cent. solution of potash; add mercuric chloride till a
precipitate is again formed; allow to settle and decant. It is used for
detecting ammonia.
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