A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Nitre.~--This is potassium nitrate.
~Platinum Chloride~, 2HCl.PtCl_{4}. (In the crystallised form it has
6H_{2}O).--It may be made as follows:--Take 5 grams of clean platinum
scrap and dissolve in a flask at a gentle heat in 50 c.c. of
hydrochloric acid with the occasional addition of some nitric acid;
evaporate to a paste; and then dissolve in 100 c.c. of water. It is used
for separating and determining potassium.
~Phenolphthalein~ is an organic compound used as an indicator; more
especially in determining the weaker acids, it cannot be used in the
presence of ammonia. Dissolve half a gram in 100 c.c. of dilute alcohol.
~Potassium Bicarbonate~, KHCO_{3}.--It may be purchased pure; on
ignition it leaves the carbonate, K_{2}CO_{3}, which may be used as a
standard.
~Potassium Cyanide~, KCN.--It is used in the dry assay as a reducing
agent. The commercial salt is very impure. Purchase that sold as
potassic cyanide (gold) which contains about 95 per cent. of KCN. It is
used for copper assaying and occasionally in separation. Make a 10 per
cent. solution when wanted.
~Potassium Bichromate~, K_{2}Cr_{2}O_{7}. It may be purchased nearly
pure. It is used as an oxidising agent, for determining iron; and as a
test solution. For this last purpose a 10 per cent. solution is
prepared.
~Potassium Chlorate~ (KClO_{3}) can be purchased pure. It is used with
hydrochloric acid as a substitute for aqua regia.
~Potassium Ferrocyanide~ (K_{4}Fe(CN)_{6}.3H_{2}O), or "yellow prussiate
of potash," is used as a test; as an indicator; and for the
determination of zinc. Make a 5 per cent. solution.
~Potassium Ferricyanide~ (K_{6}Fe_{2}(CN)_{12}), or "red prussiate of
potash," is used for testing; and as an indicator. Make a 5 per cent.
solution when wanted, as it decomposes on keeping.
~Potassium Hydrate~, KHO. Purchase that purified with alcohol. It is an
alkali, and is used for absorbing carbonic acid, &c.
~Potassium Iodide~, KI. It may be purchased nearly pure. It is used as a
test and for dissolving iodine. It should be used in a 10 per cent.
solution freshly made. The solution decomposes on exposure to light,
with separation of iodine.
~Potassium Nitrate~ (KNO_{3}) can be purchased pure. It is used in the
dry way as an oxidizing agent. It is very fusible. It decomposes at a
low temperature into potassium nitrite (KNO_{2}) and free oxygen; and at
a higher temperature leaves potash (K_{2}O). It oxidizes sulphur and
carbon with explosive violence. This action may be moderated by mixing
the nitre with carbonate of soda, common salt, or some other inert body.
~Potassium Nitrite~, KNO_{2}.--The commercial article is not pure, but
is sufficiently so for the purpose required. A saturated solution is
used in the separation of cobalt; the solution is made when wanted.
~Potassium Permanganate~, KMnO_{4}.--This salt can be purchased
sufficiently pure. It is much used as an oxidizing agent.
Public-domain text, read in full here on John Shaqi.
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