A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
But if in these examples the composition is calculated, not on 100
parts, but on 107, 246, 163, and 120 parts respectively, evidence of a
simple law becomes apparent.
Realgar. Orpiment. Mispickel. Pyrites.
Arsenic 75.0 150.0 75.0 --
Sulphur 32.0 96.0 32.0 64.0
Iron -- -- 56.0 56.0
------ ------ ------ ------
107.0 246.0 163.0 120.0
It will be seen that the proportion of arsenic is 75 or twice 75, that
of iron is 56, and that of sulphur 32 or some simple multiple of 32. The
series of examples might be extended indefinitely, and it would still be
found that the "combining proportions" held good. The number 75 is
spoken of as the "combining weight," or, more frequently, as the "atomic
weight" of arsenic. Similarly 56 is the atomic weight of iron, and 32
the atomic weight of sulphur. The importance of this law of chemical
combination is altogether independent of the atomic theory; but this
theory furnishes the simplest explanation of the facts. According to it
a chemical compound is made up of exactly similar groups of particles.
The particles of each elementary substance are all alike, but differ
from those of other elements in weight. Ultimate particles are called
_atoms_, and the groups of atoms are called _molecules_. The atomic
weight of any particular element is the weight of its atom compared with
the weight of an atom of hydrogen. The atom of sulphur, for instance, is
32 times as heavy as the atom of hydrogen, and the atomic weight of
sulphur is 32. The _molecular weight_ is the sum of the atomic weights
of the group. The molecule of pyrites contains two atoms of sulphur and
one of iron: on referring to the table of atomic weights it will be seen
that the atomic weights are--sulphur 32, and iron 56. The molecular
weight, therefore, is 32+32+56--that is, 120. The meaning of this
is, 120 parts by weight of iron pyrites contain 64 parts of sulphur and
56 parts of iron; and this is true whether the "parts by weight" be
grains or tons.
_The symbol or formula of an atom_ is generally the initial letter or
letters of the Latin or English name of the substance. The atom of
hydrogen is written H, that of oxygen O, of sulphur S, of iron (ferrum)
Fe, and so on. A list of these symbols is given in the table of atomic
weights.
_The formula of a molecule_ is obtained by placing together the symbols
of the contained atoms. Thus, Fe represents an atom of iron, S an atom
of sulphur, while FeS represents the molecule of sulphide of iron as
containing one atom of each element.
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