A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
When more than one atom of an element is present this is shown by
writing a figure under and after the symbol; thus, FeS_{2} represents a
molecule with one atom of iron and two atoms of sulphur, Fe_{2}S_{3}
similarly shows one with two atoms of iron and three of sulphur. When a
group of atoms is enclosed in brackets, a figure after and under the
bracket multiplies all within it; for example, Pb(NO_{3})_{2} is another
way of writing PbN_{2}O_{6}. Sometimes it is convenient to represent the
atoms of a molecule as divided into two or more groups; this may be done
by writing the formulæ of the groups, and separating each simple formula
by a full stop. Slaked lime, for instance, has the formula CaH_{2}O_{2};
or, as already explained, we may write it Ca(HO)_{2}; or, if for
purposes of explanation we wished to look on it as lime (CaO) and water
(H_{2}O), we could write it CaO.H_{2}O. A plus sign (+) has a different
meaning; CaO + H_{2}O indicates quantities of two substances, water and
lime, which are separate from each other. The sign of equality (=) is
generally used to separate a statement of the reagents used from another
statement of the products of the reaction; it may be translated into the
word "yields" or "becomes." The two statements form an equation.
Ignoring the quantitative relation, the meaning of the equation CaO +
H_{2}O = CaO.H_{2}O is: "lime and water yield slaked lime." By referring
to a table of atomic weights we can elicit the quantitative relations
thus:--
CaO + H_{2}O = CaH_{2}O_{2}
| | |
V V V
Ca = 40 H_{2} = 2 = 1×2 Ca = 40
O = 16 O = 16 H_{2} = 2 = 1×2
-- -- O_{2} = 32 = 16×2
56 18 --
74
Or, putting it in words, 56 parts of lime combine with 18 parts of water
to form 74 parts of slaked lime. This equation enables one to answer
such a question as this:--How much lime must be used to produce 1 cwt.
of slaked lime? for, if 74 lbs. of slaked lime require 56 lbs. of lime,
112 lbs. will require (56×112)/74, or about 84-3/4 lbs.
As another example having a closer bearing on assaying take the
following question:--"In order to assay 5 grams of 'black tin' (SnO_{2})
by the cyanide process, how much potassic cyanide (KCN) will be
required?" The reaction is
SnO_{2} + 2KCN = Sn + 2KCNO
| |
V V
Sn = 118 K = 39
O_{2} = 32 C = 12
--- N = 14
150 --
65×2 = 130
What is sought for here is the relation between the quantities of
SnO_{2} and KCN. Note that a figure before a formula multiplies all that
follows up to the next stop or plus or equality sign. The question is
now resolved to this: if 150 grams of oxide of tin require 130 grams of
cyanide, how much will 5 grams require?
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