A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
150 : 130 :: 5 : _x_
_x_ = 4.33 grams.
A problem of frequent occurrence is to find the percentage composition
of a substance when its formula has been given. For example: "What
percentage of iron is contained in a mineral having the formula
2Fe_{2}O_{3}.3H_{2}O?" Bringing this formula together we have
Fe_{4}H_{6}O_{9}. Find the molecular weight.
Fe_{4} = 224 = 56×4
H_{6} = 6 = 1×6
O_{9} = 144 = 16×9
---
374
Then we get: 374 parts of the mineral contain 224 of iron. How much will
100 contain?
374 : 224 :: 100 : _x_
_x_ = 59.89.
And the answer to the question is 59.89 per cent.
Again, suppose the question is of this kind:--"How much crystallised
copper sulphate (CuSO_{4}.5H_{2}O) will be required to make 2 litres of
a solution, 1 c.c. of which shall contain 0.0010 gram of copper?"
A litre is 1000 c.c., so, therefore, 2 litres of the solution must
contain 0.001 gram × 2000, or 2 grams. How much crystallised copper
sulphate will contain this amount of metal?
Cu = 63.3
S = 32.0
O_{4} = 64.0 = 16×4
5H_{2}O = 90.0 = 18×5
-----
249.3
If 63.3 grams of copper are contained in 249.3 grams of sulphate, in how
much is 2 grams contained.
63.3 : 249.3 :: 2 grams : _x_
_x_ = 7.8769 grams.
The answer is, 7.8769 grams must be taken.
As a sample of another class of problem similar in nature to the last
(but a little more complicated) take the following:--"What weight of
permanganate of potash must be taken to make 2 litres of a solution, 100
c.c. of which shall be equivalent to 1 gram of iron?" In the first place
the 2 litres must be equivalent to 20 grams of iron, for there are 20 ×
100 c.c. in two litres. In the titration of iron by permanganate
solution there are two reactions. First in dissolving the iron
Fe + H_{2}SO_{4} = FeSO_{4} + H_{2}
|
V
56
and second, in the actual titration,
10FeSO_{4} + 2KMnO_{4} + 9H_{2}SO_{4}= 2MnSO_{4}
| + 5Fe_{2}(SO_{4})_{3} + 2KHSO_{4} + 8H_{2}O
V
K = 39
Mn = 55
O_{4}= 64
---
158 × 2 = 316
As before, attention is confined to the two substances under
consideration--viz., Fe and KMnO_{4}. In the second equation, we find
316 parts of the permanganate are required for 10 molecules of FeSO_{4};
and in the first equation 56 parts of iron are equivalent to one
molecule of FeSO_{4}, therefore 560 of iron are equivalent to 316 of
permanganate; and the question is, How much of the permanganate will be
equivalent to 20 grams of iron?
560 : 316 :: 20 grams : _x_.
_x_= 11.286 grams.
The answer is 11.286 grams.
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