A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
Trimming the results of an analysis to make them fit in more closely
with the calculations from the formula would be foolish as well as
dishonest. There can be no doubt that the actual analytical results
represent the composition of the specimen much more closely than the
formula does; although perhaps other specimens of the same mineral would
yield results which would group themselves better around the calculated
results than around those of the first specimen analysed. It must be
remembered that substances are rarely found pure either in nature or in
the arts; so that in most cases the formula only gives an approximation
to the truth. In the case of hydrated salts there is generally a
difficulty in getting the salt with exactly the right proportion of
water.
PRACTICAL EXERCISES.
The following calculations may be made:--
1. Calculate standards in the following cases--
(a) Silver taken, 1.003 gram. Standard salt used, 100.15 c.c.
(b) Iron taken, 0.7 gram. Bichromate used, 69.6 c.c.
2. Calculate percentages:--
(a) Ore taken, 1 gram. Solution used, 65.2 c.c. Standard, 0.987
gram.
(b) Ore taken, 1 gram. Barium sulphate got, 1.432 gram. Barium
sulphate contains 13.73 per cent. of sulphur, and the percentage
of sulphur in the ore is wanted.
(c) Barium sulphate is BaSO_{4}. Calculate the percentage of sulphur
it contains, for use in the preceding question.
3. A method of estimating the quantity of peroxide in a manganese ore
is based on the following reactions:--
(1) MnO_{2} + 4HCl = MnCl_{2} + Cl_{2} + 2H_{2}O.
(2) Cl + KI = KCl + I.
To how much MnO_{2} is 1 gram of Iodine (I) equivalent?
4. A mineral has the following composition:--
Carbonic acid (CO_{2}) 19.09
Copper oxide (CuO) 71.46
Water (H_{2}O) 9.02
What is its formula?
5. How much copper is contained in 1.5 gram of crystallized copper
sulphate (CuSO_{4}.5H_{2}O)? How much of these crystals must be taken to
give 0.4 gram of copper?
6. How much ferrous sulphate crystals (FeSO_{4}.7H_{2}O) must be taken
to yield 2 litres of a solution, 100 c.c. of which shall contain 0.56
gram of iron?
7. Galena is PbS, and hæmatite Fe_{2}O_{3}. What percentages of metal do
these minerals contain?
CHAPTER VIII.
SPECIFIC GRAVITY.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account