A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The relation of the weight of a substance to its volume should be kept
in mind in all cases where both weight and volume are dealt with.
Students are apt to imagine that on mixing equal volumes of, say,
sulphuric acid and water, an acid of half the strength must be obtained.
If the statement of strength is in parts by weight this will lead to
considerable error. For example, 100 c.c. of sulphuric acid containing
98 per cent. by weight of real acid, will, if diluted with 100 c.c. of
water, yield a solution containing not 49 per cent. by weight, but about
63.5 per cent. of the acid. The reason is this: the 100 c.c. of
sulphuric acid weighs 184 grams, and contains 180.32 grams of real acid,
while the 100 c.c. of water weighs only 100 grams; the mixed water and
acid weighs 284 grams, and contains 180.32 of real acid, which is
equivalent to nearly 63.5 per cent. by weight. If, however, the method
of statement be volumetric, it would be correct to say that doubling the
volume halves the strength: if 100 c.c. of brine contains 10 grams of
salt, and is diluted with water to 200 c.c., it would be of one-half the
former strength, that is, 100 c.c. of the solution would contain 5 grams
of salt.
This confusion is avoided by always stating the strengths as so many
grams or "c.c." in 100 c.c. of the liquid. But obviously it would be
advantageous to be able to determine quickly the weight of any
particular substance corresponding to 1 c.c. or some other given volume.
Moreover, in descriptions of processes the strengths of acids and
solutions are frequently defined neither by their gravimetric nor
volumetric composition, but by a statement either of specific gravity or
of the degrees registered by Twaddell's or Beaumé's hydrometer. Thus, in
the description of the process of gold parting, one writer gives: "The
acid should be of 1.2 specific gravity"; and another says: "The acid
must not be stronger than 32° Beaumé."
These considerations justify an account of the subject in such a work as
this. And on other grounds the determination of a specific gravity is
one of the operations with which an assayer should be familiar.
The meaning of "specific gravity" is present in the mind of every one
who uses the sentence "lead is heavier than water." This is meaningless
except some such phrase as "bulk for bulk" be added. Make the sentence
quantitative by saying: "bulk for bulk lead is 11.36 times heavier than
water," and one has the exact meaning of: "the specific gravity of lead
is 11.36." A table of the specific gravities of liquids and solids shows
how many times heavier the substances are than water.
Public-domain text, read in full here on John Shaqi.
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