A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
[Illustration: FIG. 34.]
In using a hydrometer, the liquid to be tested is placed in a cylinder
(fig. 34) tall enough to allow the instrument to float, and not too
narrow. The temperature is taken, and the hydrometer is immersed in the
fluid. The mark on the hydrometer stem, level with the surface of the
liquid, is read off. With transparent liquids it is best to read the
mark under and over the water surface and take the mean.
The graduation of hydrometers is not made to any uniform system. Those
marked in degrees Baumé or Twaddell, or according to specific gravity,
are most commonly used. The degrees on Baumé's hydrometer agree among
themselves in being at equal distances along the stem; but they are
proportional neither to the specific gravity, nor to the percentage of
salt in the solution. They may be converted into an ordinary statement
of specific gravity by the following formulæ:--
Sp. g. = 144.3/(144.3-degrees Baumé.)
or putting the rule in words, subtract the degrees Baumé from 144.3, and
divide 144.3 with the number thus obtained. For example: 32° Baumé
equals a sp. g. of 1.285.
144.3/(144.3-32) = 144.3/(112.3) = 1.285
This rule is for liquids heavier than water; for the lighter liquids the
rule is as follows:--
Sp. g. = 146/(136 + degrees Baumé.)
or in words divide 146 by the number of degrees Baumé added to 136. For
example: ammonia of 30° Beaumé has a sp. g. of 0.880 (nearly).
146/(136+30) = 146/166 = 0.8795
A simple series of calculations enables one to convert a Beaumé
hydrometer into one showing the actual sp. g. Graduation, according to
sp. g. is the most convenient for general purposes. In these instruments
the distances between the divisions become less as the densities
increase.
Twaddell's hydrometer is graduated in this way: Each degree Twaddell is
0.005 in excess of unity. To convert into sp. g. multiply the degrees
Twaddell by 0.005, and add 1. For example: 25° Twaddell equals a sp. g.
of 1.125.
25×.005 = 0.125; + 1.000 = 1.125.
There is a practice which ignores the decimal point and speaks of a sp.
g. of 1125 instead of 1.125. In some cases it is convenient, and
inasmuch as no substance has a real sp. g. of much over 20, it can lead
to no confusion. The figures expressed in this way represent the weight
of a litre in grams.
Some hydrometers are graduated so as to show at a glance the percentage
composition of the liquid they are intended to be used with. Gay-Lussac
designed one to show the alcoholic strength of mixtures of alcohol and
water; the construction of others upon the same principle is easy and
perhaps useful. But when the principle is applied to complex liquids and
mixed solutions, it is misleading.
The various methods of graduation ought all to give place to one showing
a simple statement of the sp. g.
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