A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The temperature of the water is of greater importance; lowering the
temperature 2° will increase the weight by 10 or 12 milligrams. A beaker
of water may be warmed or cooled to the required temperature; then the
bottle is filled from it, and quickly weighed. If the balance-room is
cooler than the water, the latter will draw back into the bottle, and a
few small bubbles of air will enter; but even in extreme cases this will
only increase the weight by a very small fraction of a milligram. There
is more trouble caused when the room is warmer, for the liquid then
expands and protrudes as a drop resting on the top of the stopper.
There will in this case be loss by evaporation, which in the case of the
more volatile liquids, such as alcohol, is serious. To prevent this
loss, as well as any that may arise by overflow, the stopper should be
dilated above into a small cup, A (fig. 36), which may itself be
stoppered. In a bottle of this kind the neck of the stopper is
graduated, and the bottle is considered full when the liquid stands at
the level of the mark in the neck. On inserting the stopper, the liquid
rises into the cup, and is reduced to the level of the mark by
absorption with pieces of filter-paper.
[Illustration: FIG. 36.]
For most purposes, however, there is no need for cooling and allowing
room for subsequent expansion. The assayer, as a rule, can select his
own standard temperature, and may choose one which will always
necessitate warming. It will be handier in this case to have a bottle
with a thermometer stopper. Of the two types shown in fig. 37, that with
the external thermometer tube (A) is more generally useful.
[Illustration: FIG. 37.]
The bottle is filled at a lower temperature, and is then gently warmed
so as to slowly raise the temperature to the required degree. The
superfluous liquid is then at once wiped off, and the bottle cooled and
weighed.
The weight of the flask filled with the liquid whose sp. g. has to be
determined is ascertained in a similar way. Of course the temperature
must be the same. If the liquid does not mix with water, the bottle
should be dried before filling, but otherwise the flask need only be
rinsed out two or three times with the liquid.
Having obtained the three weighings, deduct the weight of the bottle
from each of the others to get the weights of the water and liquid
respectively. Divide the latter by the former, the result shows the sp.
g. As an example, take the following, in which a rather large sp. g.
bottle was used:--
1. Weight of bottle 39.299 gram
2. Weight of bottle and water 81.884 "
3. Weight of bottle and paraffin 73.146 "
By subtracting 1 from 2 and 3 the result is as follows:--
81.884 grams 73.146 grams
39.299 " 39.299 "
------ ------
42.585 of water. 33.847 of paraffin.
Divide the weight of the paraffin by that of the water--
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