A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The next in order is what is called 60 per cent. white. It {178}
consists of a hard white mass, requiring considerable force to break
it. Though whiter in appearance than cream caustic, it is in reality
less pure, as it contains a considerable quantity of salt. It is made
by continuing the evaporation of the caustic liquor to a further point
than is the case with cream caustic, the result being that the whole
of the water is driven off. A small quantity of nitre is then added to
oxidise the sulphides and other compounds which impart the colour to
cream caustic. Common salt is then added to reduce its strength to 60
per cent., in order to satisfy the whim of the consumer, who insists
upon an article of a given definite strength. On this account it is
somewhat inferior to cream caustic, and is, moreover, more expensive.
The highest quality of all is white 70 per cent. This resembles white
60 per cent. in appearance, but is much purer, and more expensive.
A very pure form of caustic soda has within the last few years been
introduced by the Greenbank Alkali Company. It consists of small
fragments, more or less crystalline, of almost pure sodium hydrate. It
can be packed in wooden casks, and it dissolves very readily in water.
It contains 76 per cent. of alkali. It is, however, much too costly for
boiling purposes; it might, however, be used for the preparation of
rosin size.
The following analyses of different forms of caustic soda and their
relative prices will possibly be of interest:—
-----------------+-----------------+-----------------+---------------
| (Davis.) | (Davis.) | (Morrison.)
| White (70 Per | White (60 Per | Cream (60 Per
| Cent. Na_{2}O). | Cent. Na_{2}O). | Cent. Na_{2}O).
-----------------+-----------------+-----------------+---------------
Sodium hydrate | 89·60 | 75·25 | 70·00
Sodium carbonate | 2·48 | 2·53 | 5·00
Sodium chloride | 3·92 | 17·40 | 7·00
Sodium sulphate | 3·42 | 4·40 | 2·00
Sodium sulphide | 0·02 | 0·03 | —
Sodium silicate | 0·30 | 0·30 | —
Sodium aluminate | trace | trace | —
Water | none | none | 15·80
Insoluble matter | none | none | 0·20
-----------------+-----------------+-----------------+---------------
{179}
Their relative prices per ton f.o.b Liverpool, in December 1886,
were:—70 per cent. white, 8_l._ 5_s._; 60 per cent. white, 7_l._ 5_s._;
60 per cent. cream, 7_l._
Public-domain text, read in full here on John Shaqi.
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