A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The percentage of cellulose yielded by this method is, in the case
of jute, usually 2–3 per cent. higher than by the bromine method.
Moreover, if the temperature be maintained at 0° C. (32° F.), by
placing the fibre, which is to be exposed to the action of the gas,
in contact with pounded ice, the percentage may be still further
increased, amounting {20} in some cases to 80–82. Corresponding to
this increased yield, the cellulose is obtained in long filaments.
It will be seen, therefore, that the cellulose isolated by chemical
treatment from a _compound cellulose_ is affected both in character
and quantity by the process employed, and it is affected in a much
greater degree than the cellulose itself exposed to the same treatment,
_after isolation_. The composition of the cellulose obtained in this
way differs from that of celluloses, such as cotton, which exist in
the plant in an isolated and more fully formed condition; it contains
43 per cent. C and 6 per cent. H, corresponding to the formula n
[3 C_{6}H_{10}O_{5}H_{2}O.] The composition of this cellulose will
be seen to be identical with that of certain of the oxycelluloses
previously described; and its properties are, moreover, those of an
oxycellulose. These facts go to show that the jute fibre substance,
and the substances allied to it, are compounds of cellulose with
other molecules, _i.e._ they are _compound celluloses_. They may be
conveniently grouped under the term _ligno-cellulose_.
_Dilute Mineral Acids._—Under the action of dilute sulphuric or
hydrochloric acid (5–10 per cent.) at 60°–80° C. (140°–176° F.), a
considerable portion of the fibre substance is dissolved. The action
of either reagent is of course purely hydrolytic; and the hydrolysis
is of the simplest character, since the substance dissolved as well as
the residual fibre are found to have the same percentage composition.
Moreover, the residual fibre, though having undergone a profound
structural modification, and having been converted into a disintegrated
mass of brittle fragments, still preserves the chemical characteristics
of the original, unaltered. Thus it is converted by the action of
chlorine into a similar complex of derivatives, yielding on resolution
by sodium sulphite solution 75 per cent. of cellulose; also when acted
upon by alkaline hypobromite it yields bromoform. Under the action of
these hydrolytic reagents, therefore, the fibre shows itself to be
essentially a chemical whole. At the boiling temperature, these acids
resolve as well as dissolve the fibre substance, and the volatile
products are acetic acid and the peculiar aldehyde {21} _furfural_
C_{4}H_{3}O.COH. The yield of this aldehyde may be raised with suitable
precautions to 15–20 per cent. of the raw fibre. The action of dilute
nitric acid upon the fibre differs from that of the above-mentioned
acids, in effecting its resolution into soluble derivatives and
insoluble cellulose; the yield of the latter when the reaction is
conducted at 60° C.
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