A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Plants are so far built up of cellulose that it may be called the
material basis of the vegetable world. Plant tissues, however, seldom,
if ever, consist of pure cellulose, but contain besides, other products
of growth either chemically combined with the cellulose or mechanically
bound up with the tissue, which are, according to the nature of their
union, removable either by means of fundamental chemical resolution
or by the application of simple solvents. A general method for the
isolation of cellulose consists in exposing the moist tissue to
the action of chlorine gas or of bromine water in the cold, and
subsequently boiling in dilute ammonia; repeating this treatment until
the alkaline solution no longer dissolves anything from the tissue or
fibre. The cellulose is then washed with water, alcohol, and ether,
and dried. Obtained in this way, or in the form of bleached cotton, or
of Swedish filter paper, it is a white substance, more or less opaque,
retaining the microscopic features of the tissue or fibre from which it
has been isolated. Its sp. gr. is 1·25–1·45. Its elementary composition
is expressed by the percentage numbers (Schulze)
C 44·0 44·2
H 6·3 6·4
O 49·7 49·4
or by the corresponding empirical formula, viz. C_{6}H_{10}O_{5}.
These numbers represent the composition of the ash-free cellulose.
Nearly all celluloses contain a certain proportion, {5} however small,
of mineral constituents, and the union of these with the organic
portion of the fibre or tissue is of such a nature that the ash left on
ignition preserves the form of the original. It is only in the growing
point of certain young shoots that the cellulose tissue is free from
mineral constituents. (Hofmeister.)
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