A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The methods of bleaching being essentially the same for all pulps, it
will only be necessary to describe one in detail.
The process depends upon the use of a solution of calcium hypochlorite,
prepared by dissolving bleaching powder in water. This solution is
best prepared in a vessel provided with stirrers or agitators, whereby
a thorough mixture of the bleaching powder and water is obtained.
Bleaching powder always contains a certain amount of free lime and
calcium carbonate, which remain undissolved in the water. This should
be allowed to settle to the bottom of the vessel, and the clear liquor
run off. The residue may then be again treated with water, or with weak
liquor obtained by washing the residue. If the washings are too weak to
be conveniently used for bleaching, they may be stored in a separate
tank and used for dissolving fresh powder. In this way a strong stock
solution can be readily prepared, the powder at the same time being
thoroughly exhausted. The washing should be repeated as frequently
as possible, after which the residue may be allowed to drain. This
operation is best conducted on a filter bed provided with an air-pump
similar to that described in Chapter XII. The residue is obtained in
this way as a hard cake, containing about 60 per cent. of water. If the
above operations have been properly conducted, it should not contain
more than about 0·25 per cent. of chlorine.
The original powder should contain from 33·0 to 35·0 per cent. of
“available chlorine,” that is, chlorine which is effective in the
bleaching process. {111}
Owing to the ease with which it decomposes it should be kept cool and
not exposed to the air.
If possible, one or more large store tanks should be provided for
the strong bleach liquor, so that time may be given for the complete
separation of the insoluble portions. The liquor can be drawn off with
a “siphon” pipe without disturbing the residue.
It is of the utmost importance that only clear liquor be used, as a
milky solution of calcium hypochlorite is much more sluggish in its
action than one which is perfectly clear and bright.
A convenient strength for the stock solution is 6° Twaddle: this
corresponds to about half a pound of bleaching powder to the gallon.
The method of testing the powder and its solution will be described in
Chapter XIV.
The washed and broken pulp is placed in the “potcher” together with
the necessary quantity of bleaching liquor and as much water as is
required to produce complete circulation of the mass. In many mills the
breaker itself answers the purpose of a potcher also. The quantity of
water should be kept as low as possible, as it is found that by the use
of strong solutions less bleaching powder is required than with weak
solutions; moreover, less time is required to produce the effect. On
the other hand, with very strong solutions, the pulp is liable to be
injuriously affected.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account