A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Straw and esparto pulps are sometimes bleached in large potchers made
of brick covered with cement. The circulation of the pulp is produced
by the action of paddles made of wood or, preferably, of iron.
Many “potchers” are provided with steam pipes, whereby the mass of pulp
and liquor is heated. This should be done with great care, so as to
avoid superheating in any part, as this is certain to cause destruction
of the fibre. The better plan, where it can be adopted, is to uniformly
heat the pulp before running in the bleach.
In certain cases the action of the calcium hypochlorite is {112}
assisted and accelerated by the addition of either sulphuric
or hydrochloric acids; these combine with the lime and liberate
hypochlorous acid, which has a more rapid action than its calcium salt.
If the acid be added in too large quantity, or of too great a strength,
it sometimes happens that instead of hypochlorous acid, chlorine gas
is given off, part of which escapes into the air, thus causing loss.
Moreover, the chlorine is liable to enter into combination with the
fibre substance forming the yellow chlorination products described on
p. 18.
This liability is greater in the case of highly lignified fibres, such
as wood or jute: in these cases, therefore, the use of acids should be
avoided. When used the acid should be largely diluted with water and
added gradually. The best plan is to allow the action of the bleach
to continue for some time, only adding the acid when it is nearly
exhausted. In this way risk of damage to the pulp is avoided.
The diluted acid should be conveyed by a leaden pipe passing down to
the floor of the potcher, and perforated at its lower extremity.
Other means of accelerating the action of the bleaching powder have
been suggested, such, for example, as the use of bicarbonate of soda,
which by double decomposition forms with the bleaching powder carbonate
of lime and free hypochlorous acid. It is, however, much too expensive
an agent.
The amount of bleaching powder necessary to produce a good white colour
differs materially with the fibre to be bleached, and of course with
the degree of resolution of the fibre substance in the preliminary
treatment with caustic soda.
The following numbers may be taken to be approximations of the amount
necessary to bleach well-boiled pulps:—
Per cent. Powder
calculated on
Unboiled Fibre.
Esparto 10 to 15
Straw 7 to 10
Wood 15 to 20
{113}
A well-boiled pulp should contain from 90 to 95 per cent. of cellulose.
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