A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Temp. Time. Weight absorbed.
H_{2}SO_{4} 4° C. (39° F.) 3 min 0·00495
HCl „ „ 0·00733
NaOH „ „ 0·02020
The molecular ratio of the absorption, in the two latter, is
3 HCl : 10 NaOH, and it is noteworthy that the same ratio was observed
for silk.
Cellulose removes barium hydrate from its solution in wafer to form
with it an insoluble compound. On adding lead acetate to the solution
of cellulose in the ammonio-copper reagent, so prepared as to contain
no carbonate, a {8} precipitate is obtained consisting of a compound of
cellulose with lead oxide, but in variable proportions. The compound
C_{6}H_{10}O_{5}PbO is formed by the action of finely-divided lead
oxide upon the above solution. Quite recently it has been shown
(O’Shea, _Chem. News_, May 28th, 1886) that when dilute solutions of
lead are passed through ordinary filter paper, a certain amount is
retained which cannot be removed by washing.
Cellulose does not combine with metallic salts, a fact which has been
established incidentally to researches upon the mode of action of
mordants.
The combinations of cellulose with acid radicles (ethereal salts) are
both definite and stable.
_Triacetyl Cellulose_ [C_{6}H_{7} (C_{2}H_{3}O)_{3} O_{5}] is formed
by treating cellulose with six times its weight of acetic anhydride at
180° C. (356° F.). The product of the reaction is a syrupy solution
from which the compound in question separates on dilution with water as
a white flocculent precipitate.
Triacetyl cellulose is insoluble in alcohol and in ether, but soluble
in glacial acetic acid. It is easily saponified by boiling with a
solution of potassium hydrate, the cellulose being regenerated. No
derivative containing more than three acetyl groups has been obtained;
but a mixture of the mono-and di-acetyl cellulose is formed in treating
cellulose with only twice its weight of acetic anhydride, the formation
of these bodies being unattended by their solution.
Whenever cellulose, in any form, is brought into contact with strong
nitric acid at a low temperature, a nitro product, or a nitrate, is
formed. The extent of the nitration depends upon the concentration of
the acid, on the time of contact of the cellulose with it, and on the
state of the physical division of the cellulose itself.
Knop, and also Kamarsch, and Heeren, found that a mixture of sulphuric
acid and nitric acid also formed nitrates of cellulose; and still later
(1847), Millon and Gaudin employed a mixture of sulphuric acid and
nitrates of soda or potash, which they found to have the same effect.
{9}
Several well characterised nitrates have been formed, but it is a very
difficult matter to prepare any one in a state of purity, and without
admixture of a higher or lower nitrated body.
The following are known:—
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