A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
Gelatin is insoluble in alcohol, ether, and cold water, but swells in
the last, absorbing about 40 per cent. It is soluble in hot water,
but is reprecipitated on the addition of a sufficient quantity of
alcohol, resembling in this respect gum, dextrin, and many other
substances. It is soluble in glycerin, with the aid of heat, and in
concentrated sulphuric acid in the cold. Moist gelatin exposed to
the air rapidly putrefies. It first becomes very acid, from formation
of butyric (and perhaps other) acids, but afterwards alkaline, from
evolution of ammonia. Boiled with concentrated potash, it yields leucin
(amidocaproic acid, C_{6}H_{15}NO_{2}), glycocin (sugar of gelatin),
and other substances. The same products are obtained by boiling with
sulphuric acid, and probably also more gradually, and in greater or
less proportions, by the prolonged action of lime or barium hydrate,
by putrefaction, and by any other influence which tends to resolve the
gelatin molecule into its simpler parts. Gelatin is precipitated by all
tannins, even from very dilute solution. A solution containing 2/10000
parts is rendered turbid by infusion of gall-nuts or gallotannic acid.
The precipitate is soluble in excess of gelatin. Solution of gelatin
dissolves considerable quantities of lime phosphate, hence this is
always largely present in common glue. Gelatin is precipitated by
mercuric chloride, in this respect resembling peptones; but not by
potassium ferrocyanide, by which it is distinguished from albuminoids;
and it differs from albumen in not being coagulated by heat. On the
contrary, by prolonged boiling glue loses the property of gelatinising,
and becomes soluble in cold water, being split up into two peptones;
semi-glutin, which is insoluble in alcohol, and precipitated by
platinic chloride; and hemicollin, which is soluble in alcohol, and not
precipitated by platinic chloride. Both are precipitated by mercuric
chloride (see Hofmeister, abst. Chem. Soc. Jour. 1881, p. 294).
Gelatin or glue with about 3 per cent. of potassium dichromate becomes
insoluble when exposed to the light, from the formation of a chromium
compound. This reaction is the base of several modern photographic
processes, and has been used for waterproofing and for cementing glass,
&c.
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