A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
The currying of crown leather is very simple. It is set out on flesh
and grain, and boarded to raise the grain. Mossner, before currying,
washes 2 hours in water and brushes with tepid soda solution (1 in
60). The yield of weight is small, only amounting to about 30-40 per
cent. of the raw hide employed, and hence the price per lb. must be
considerably higher than that of tanned leather to yield a profit. The
above information is mostly drawn from articles by W. Eitner ('Der
Gerber,' iv. 1 _et seq._) and Franz Kathreiner ('Gerber Zeitung,' 21st
December, 1875).
CHAPTER XIX.
MINERAL-TANNED LEATHER.
The invention of the earliest form of mineral tanning, that with alum
and salt, dates from remote antiquity; but as it is in large measure
the type of all that has been since done, it deserves examination in
some detail, at least as regards principles. In practice it is used
alone in curing skins with the hair on, and for making white leather
for laces and other purposes; and, in combination with oil and albumen,
which, as we have seen, are the tanning agents in the case of "crown
leather," it forms the process for producing calf and glove kids, as
will be described under those headings (pp. 223, 225).
Careful researches by Reimer (Ding. Polyt. Jour., 205, p. 143 _et
seq._) show (what has long been known in practice) that alum alone
is not capable of making a pliable leather. The salt, nevertheless,
does not enter into combination with the alum, or even with the hide.
Its function is partially physical, increasing the diffusion of the
solution, and partially chemical, as in the presence of acids (and
salts of acid reaction) it precipitates the coriin, and prevents it
from gluing the fibres into a horny mass as it dries. Prof. Knapp
has shown that this is the first essential in producing leather, and
that raw hide may be converted into a pliable material with all the
properties of white leather by simply withdrawing the water with
alcohol, in which coriin is not soluble, and by which it is therefore
precipitated. This leather, containing when dried no added constituent,
is of course at once reconverted into raw hide by soaking in water.
Both the salt and a portion of the alumina is removed from tawed
leather by soaking in water, and it then dries hard and horny, and
by boiling in water will yield a considerable percentage of gelatin.
The alum is not absorbed as a whole. It is a double salt (alumina and
potash sulphate or alumina and ammonia sulphate), and only the alumina
sulphate is absorbed, potash (or ammonia) sulphate accumulating in the
liquor. The alumina salt retained by the hide, especially in presence
of much salt, contains slightly more than its normal proportion of
alumina to acid, or in chemical language is to some extent basic. This
is caused partly by the lime remaining in the skin from the unhairing
process, which neutralises a portion of sulphuric acid, but in part is
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