A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
the result of the affinity of the hide-fibres for alumina, a certain
small proportion of free sulphuric acid being left in the liquor. The
accumulation of this and of potash sulphate is the reason why such
liquors cannot be used perpetually by mere strengthening with alum, but
must be frequently renewed. The attraction of hide-fibre for alumina
sulphate is so strong, that in presence of a sufficient excess of
hide it may be completely removed even from dilute solutions. Alumina
acetate or sulphate may be substituted for alum with equally good
results in practice, the only advantage of the latter being its easier
preparation. Ferric and chromic salts and iron or chrome alum, may be
substituted for common alum, and are absorbed in a similar manner, and
in presence of common salt give equally pliable leathers, of a buff
and pale greenish tint respectively. Without salt, the leathers are
hard and brittle. In all these cases, the tanning agent may be to a
large extent removed by simple washing with water. The tannage may be
rendered more durable by passing the leather before drying through a
weak bath of sodic carbonate or even lime-water, which precipitates the
alumina, iron, or chrome in a basic form on the hide-fibres. Soap baths
may also be used, by which aluminic, ferric, or chromic stearates and
oleates are formed, possessing considerable toughness and resistance to
water. So far as the writer is aware, no mineral tannage has yet been
produced which will not yield gelatin when treated, first with dilute
acid and then with boiling water; but this is rather a gain than
otherwise, as leather scraps might be utilised for glue. There seems
no reason why good and durable leather, for boot-uppers and for many
mechanical purposes, should not be fabricated with salts of iron and
chromium in conjunction with salt. If eggs and flour were also used,
products similar to calf-kid would be obtained. Iron-leathers may of
course be blacked with infusions of galls or many tanning materials, or
with logwood. Ferrous salts have no tanning properties.
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