A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
7. " " " magnesium chloride, 20° do. Not at all plumped.
8. " " " common salt, 20° do. do. do.
(1 German degree of hardness corresponds to 1 of lime in 100,000.)
The peculiarities which were shown by the hide pieces on removal
from the water were maintained throughout the tanning, which was
conducted in imitation of the German method, the hide being swollen
and coloured through in weak birch-bark liquors, made with distilled
water and acidified in each case with equal quantities of lactic
acid, and finally laid away till tanned in a mixture of oak bark and
valonia. No. 6, from magnesia sulphate, was the best; then No. 2; No.
3 was less good, but all the pieces from 1 to 6 were firm, close,
and of good substance and texture, No. 1 having swelled well in the
sour liquor. On the other hand, 7 and 8 scarcely swelled in liquor,
but remained flat throughout, and were looser, thinner, and of finer
fibre. From this experiment it is clear that while sulphates and
carbonates exert a favourable influence on plumping, chlorides do the
reverse, not only not plumping themselves, but placing the hides in an
unfavourable condition for the plumping action of acids in the liquors.
These experiments are quite borne out by the writer's experience in
practice. The water at the Lowlights Tannery, which in dry weather
is mostly obtained from beds of what was originally sea-sand, and
which consequently contains a very abnormal proportion of chlorides
(up to 68 pts. NaCl per 100,000), requires special and very careful
management to make thick leather, notwithstanding its containing a
considerable quantity of calcium and magnesium sulphates. These facts
also indicate the importance of the thorough removal of salt from hides
intended for sole-leather. Plumping is not a desirable thing in leather
intended for dressing purposes, and it is possible that the use of a
small percentage of salt in the liquors or wash waters might enable
bating to be dispensed with. Like a bate, salt would dissolve a small
proportion of hide substance (see p. 19). There is no practicable means
of removing chlorides from water, but Eitner suggests the addition of
a small quantity of sulphuric acid to water containing much temporary
hardness (bicarbonates), by which it is converted into permanent
(sulphates), which, as we have seen, plumps better. For this purpose
about 2·8 oz. of ordinary English vitriol (sp. gr. 1·490) per 100 cub.
ft. of water is required for each part of lime Ca(OH)_{2} per 100,000
(see p. 97 for testing of water). A simpler guide is to add enough to
purple, but not to redden litmus paper, even after moving it about in
the water for some minutes. The acid must of course be well mixed by
plunging. It must be borne in mind that Eitner's experiment was on
sweated hides, and that with limed hide, which is kept plump by the
dissolved lime retained in the hide, the conditions are different,
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