A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
and different results as regards carbonic acid and bicarbonates would
probably be obtained. Both these would convert the lime in the hide
into chalk, which is both insoluble and inert, and the hide would
probably fall, at any rate till the lime was completely carbonated,
while hides would remain plumpest in waters most free from substances
capable of neutralising lime. One of the waters most effective in
plumping limed hides is that of the river at Lincoln. Its hardness
and contents in chlorine is, as compared with Lowlights water in dry
weather,
Per 100,000.
_Lincoln_, permanent hardness 8·43, temporary 8·32, chlorine 2·60 pt.
_Lowlights_, " " 60·5, " 45·0 " 41·7 "
Both waters have a considerable quantity of organic matter, and both
owe their hardness in part to magnesia. From this we might conclude,
what may be _à priori_ expected, that the softer the water, the plumper
limed hides remain in it. I am informed, however, by Mr. S. L. Evans,
that in the Dartmoor water, which is very soft, but peaty, hides fall
rapidly. In this case the colouring matters of the peat, which are
of the nature of very weak acids, probably neutralise the lime. It
may also be remarked, that wherever the conditions of putrefaction or
decaying organic matter is present, hides rapidly fall, for the same
reasons as they do in a bate.
While the injurious effect of bicarbonates on limed hide is matter of
common experience, their influence on liquors and tanning is not so
well understood. It is certain that they neutralise and combine with
the organic acids of the liquors, and probably with some species of
tannin, and as 1 part per 100,000 amounts to 1 oz. per 100 cub. ft.,
the acid required to neutralise a very hard water amounts to something
considerable. It is well known that hard waters make bad tea, and the
influence of hardness on the extraction of tannin is a subject well
worthy of investigation, and which the writer hopes to examine.
On dyeing, at least as regards dye-woods, the influence of bicarbonates
is distinctly favourable, and this is also stated to be true of woad,
cochineal, and indigo-carmine.
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