A Treatise on Adulterations of Food, and Culinary Poisons: Exhibiting the Fraudulent Sophistications of Bread, Beer, Wine, Spiritous Liquors, Tea, Coffee, Cream, Confectionery, Vinegar, Mustard, Pepper, Cheese, Olive Oil, Pickles, and Other Articles Employed in Domestic EconomyAccum, Friedrich Christian
Science
A Treatise on Adulterations of Food, and Culinary Poisons: Exhibiting the Fraudulent Sophistications of Bread, Beer, Wine, Spiritous Liquors, Tea, Coffee, Cream, Confectionery, Vinegar, Mustard, Pepper, Cheese, Olive Oil, Pickles, and Other Articles Employed in Domestic Economy
Accum, Friedrich Christian
Food adulteration and inspection
Take a bottle (_a_) or Florence flask, adapt to the mouth of it a cork
furnished with a glass tube (_b_), bent at right angles; let one leg of
the tube be immersed in the vial (_c_) containing the water to be
examined; as shewn in the following sketch. Then take one part of
sulphuret of antimony of commerce, break it into pieces of half the size
of split pease, put it into the flask, and pour upon it four parts of
common concentrated muriatic acid (spirit of salt of commerce).
Sulphuretted hydrogen gas will become disengaged from the materials in
abundance, and pass through the water in the vial (_c_). Let the
extrication of the gas be continued for about five minutes; and if the
minutest quantity of lead be present, the water will acquire a
dark-brown or blackish tinge. The extrication of the gas is facilitated
by the application of a gentle heat.
The action of the sulphuretted hydrogen test, when applied in this
manner, is astonishingly great; for one part of acetate of lead may be
detected by means of it, in 20000 parts of water.[24]
Another test for readily detecting lead in water, is sulphuretted
chyazate of potash, first pointed out as such by Mr. Porret. A few drops
of this re-agent, added to water containing lead, occasion a white
precipitate, consisting of small brilliant scales of a considerable
lustre.
Sulphate of potash, or sulphate of soda, is likewise a very delicate
test for detecting minute portions of lead. Dr. Thomson[25] discovered,
by means of it, one part of lead in 100000 parts of water; and this
acute Philosopher considers it as the most unequivocal test of lead that
we possess. Dr. Thomson remarks that "no other precipitate can well be
confounded with it, except sulphate of barytes; and there is no
probability of the presence of barytes existing in common water."
Carbonate of potash, or carbonate of soda, may also be used as agents to
detect the presence of lead. By means of these salts Dr. Thomson was
enabled to detect the presence of a smaller quantity of lead in
distilled water, than by the action of sulphuretted hydrogen. But the
reader must here be told, that the use of these tests cannot be
entrusted to an unskilful hand; because the alkaline carbonates throw
down also lime and magnesia, two substances which are frequently found
in common water; the former tests, namely, water impregnated with
sulphuretted hydrogen gas, and nascent sulphuretted hydrogen, are
therefore preferable.
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