Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
_Freezing-Points of Calcium Chloride Solutions._
_________________________________________________________
| | | |
| Percentage of | Specific Gravity. | Freezing-point. |
| CaCl_2. | | |
|_______________|___________________|_____________________|
| | | | |
| | | Degs. C. | Degs. F. |
| 6 | 1.05 | -3.0 | +26.6 |
| 8 | 1.067 | 4.3 | 24.3 |
| 10 | 1.985 | 5.9 | 21.4 |
| 12 | 1.103 | 7.7 | 18.1 |
| 14 | 1.121 | 9.8 | 14.4 |
| 16 | 1.140 | 12.2 | 10.0 |
| 18 | 1.159 | 15.2 | 4.6 |
| 20 | 1.170 | 18.6 | -1.5 |
|_______________|___________________|__________|__________|
Calcium chloride will probably be procured in the solid state, but it can
be purchased as a concentrated solution, being sold under the name of
"calcidum" [Footnote: This proprietary German article is a liquid which
begins to solidify at -42° C. (-43.6° F.), and is completely solid at
-56° C. (-69)° F.). Diluted with one-third its volume of water, it
freezes between -20° and -28° C. (-4° and-l8.4° F.). The makers recommend
that it should be mixed with an equal volume of water. Another material
known as "Gefrierschutzflüssigkeit" and made by the Flörsheim chemical
works, freezes at -35° C. (-3° F.). Diluted with one-quarter its volume
of water, it solidifies at -18° C. (-0.4° F.); with equal parts of water
it freezes at -12° C. (10.4° F.). A third product, called "calcidum
oxychlorid," has been found by Caro and Saulmann to be an impure 35 per
cent. solution of calcium chloride. Not one of these is suitable for
addition to the water used in the generating chamber of an acetylene
apparatus, the reasons for this having already been mentioned.] for the
protection of gasholder seals. Glycerin itself resembles a strong
solution of calcium chloride in being a viscid, oily-looking liquid; and
both are so much heavier than water that they will not mix with further
quantities unless they are thoroughly agitated therewith. Either may be
poured through water, or have water floated upon it, without any
appreciable admixture taking place; and therefore in first adding them to
the seal great care must be taken that they are uniformly distributed
throughout the liquid. If the whole contents of the seal cannot
conveniently be run into an open vessel in which the mixing can be
performed, the sealing water must be drawn off a little at a time and a
corresponding quantity of the protective reagent added to it. Care must
be taken also that motives of economy do not lead to excessive dilution
of the reagent; the seal must be competent to remain liquid under the
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