Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
lighted is in common use on some railways, where passengers' foot-warmers
are filled with a strong solution of sodium acetate. When sodium acetate
is dissolved in water it manifestly exists in the liquid state, and it is
presumably present in its anhydrous condition (i.e., not combined with
water of crystallisation). The common crystals are solid, and contain 3
molecules of water of crystallisation--also clearly in the solid state.
Now, the reaction
NaC_2H_3O_2 + 3H_2O = NaC_2H_3O_2.3H_2O
(anhydrous acetate) (crystals)
evolves 4.37 calories (Berthelot), or 1.46 calorie for each molecule of
water; and whereas 1 kilo. of water only evolves 1 large calorie of heat
as its temperature falls 1° C., 18 grammes of water (1 gramme-molecule)
evolve l.46 large calorie when they enter into combination with anhydrous
sodium acetate to assist in forming crystals--and this 1.46 calorie may
either be permitted to warm the mass of crystals, or made to do useful
work by raising the temperature of some adjacent substance. Sodium
acetate crystals dissolve in 3.9 parts by weight of water at 6° C. (43°
F.) or in 2.4 parts at 37° C. (99° F.). If, then, a jacket round an
acetylene apparatus is filled with a warm solution of sodium acetate
crystals in (say) 3 parts by weight of water, the liquid will crystallise
when it reaches some temperature between 99° and 43° F.; but when the
generator comes into action, the heat liberated will change the mass of
crystals into a liquid without raising its sensible temperature to
anything like the extent that would happen were the jacket full of simple
water. Not being particularly warm to the touch, the liquefied product in
the jacket will not lose much heat by radiation, &c., into the
surrounding air; but when the water in the generator falls again (after
evolution of acetylene ceases) the contents of the jacket will also cool,
and finally will begin to crystallise once more, passing a large amount
of low-temperature heat into the water of the generator, and safely
maintaining it for long periods of time at a temperature suitable for the
further evolution of gas. Like the liquid in the seal of an isolated
gasholder, the liquid in such a jacket will last indefinitely; and
therefore the cost of the sodium acetate in negligible.
Public-domain text, read in full here on John Shaqi.
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