Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Another method of keeping warm the water in any part of an acetylene
installation consists in piling round the apparatus a heap of fresh
stable manure, which, as is well known, emits much heat as it rots. Where
horses are kept, such a process may be said to cost nothing. It has the
advantage over methods of lagging or jacketing that the manure can be
thrown over any pipe, water-seal, washing apparatus, &c., even if the
plant is constructed in several separate items. Unfortunately the ammonia
and the volatile organic compounds which are produced during the natural
decomposition of stable manure tend seriously to corrode iron and steel,
and therefore this method of protecting an apparatus from frost should
only be employed temporarily in times of emergency.
CORROSION IN APPARATUS.--All natural water is a solution of oxygen and
may be regarded also as a weak solution of the hypothetical carbonic
acid. It therefore causes iron to rust more or less quickly; and since no
paint is absolutely waterproof, especially if it has been applied to a
surface already coated locally with spots of rust, iron and steel cannot
be perfectly protected by its aid. More particularly at a few inches
above and below the normal level of the water in a holder, therefore, the
metal soon begins to exhibit symptoms of corrosion which may eventually
proceed until the iron is eaten away or becomes porous. One method of
prolonging the life of such apparatus is to give it fresh coats of paint
periodically; but unless the old layers are removed where they have
cracked or blistered, and the rust underneath is entirely scraped off
(which is practically impossible), the new paint films will not last very
long. Another more elegant process for preserving any metal like iron
which is constantly exposed to the attack of a corrosive liquid, and
which is readily applicable to acetylene holders and their tanks, depends
on the principle of galvanic action. When two metals in good electrical
contact are immersed in some liquid that is capable of attacking both,
only that metal will be attacked which is the more electro-positive, or
which (the same thing in other words) is the more readily attacked by the
liquid, evolving the more heat during its dissolution. As long as this
action is proceeding, as long, that is, as some of the more electro-
positive material is present, the less electro-positive material will not
suffer. All that has to be done, therefore, to protect the walls of an
acetylene-holder tank and the sides of its bell is to hang in the seal,
supported by a copper wire fastened to the tank walls by a trustworthy
electrical joint (soldering or riveting it), a plate or rod of some more
electro-positive metal, renewing that plate or rod before it is entirely
eaten away. [Footnote: Contact between the bell and the rod may be
established by means of a flexible metallic wire; or a separate rod might
be used for the bell itself.] If the iron is bare or coated with lead
Public-domain text, read in full here on John Shaqi.
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