Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
FROTHING IN GENERATORS.--A very annoying trouble which crops up every now
and then during the evolution of acetylene consists in the production of
large masses of froth within the generator. In the ordinary way,
decomposition of carbide is accompanied by a species of effervescence,
but the bubbles should break smartly and leave the surface of the liquid
reasonably free from foam. Sometimes, however, the bubbles do not break,
but a persistent "head" of considerable height is formed. Further
production of gas only increases the thickness of the froth until it
rises so high that it is carried forward through the gas-main into the
next item of the plant. The froth disappears gradually in the pipes, but
leaves in them a deposit of lime which sooner or later causes
obstructions by accumulating at the angles and dips; while during its
presence in the main the steady passage of gas to the holder is
interrupted and the burners may even be made to jump. Manifestly the
defect is chiefly, if not always, to be noticed in the working of
carbide-to-water generators. The phenomenon has been examined by
Mauricheau-Beaupré, who finds that frothing is not characteristic of pure
carbide and that it cannot be attributed to any of the impurities
normally present in commercial carbide. If, however, the carbide contains
calcium chloride, frothing is liable to occur. A 0.1 per cent. solution
of calcium chloride appears to yield some foam when carbide is decomposed
in it, and a 1 per cent. solution to foam in a pronounced manner. In the
absence of calcium chloride, the main cause of frothing seems to be the
presence in the generator of new paint or tar. If a generator is taken
into use before the paint in any part of it which becomes moistened by
warm lime-water has had opportunity of drying thoroughly hard, frothing
is certain to occur; and even if the carbide has been stored for only a
short time in a tin or drum which has been freshly painted, a production
of froth will follow when it is decomposed in water. The products of the
polymerisation of acetylene also tend to produce frothing, but not to
such an extent as the turpentine in paint and the lighter constituents of
coal-tar. Carbide stored even temporarily in a newly painted tin froths
on decomposition because it has absorbed among its pores some of the
volatile matter given off by the paint during the process of desiccation.
Public-domain text, read in full here on John Shaqi.
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