Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
THE "DRY" PROCESS OF GENERATION.--A process for generating acetylene,
totally different in principle from those hitherto considered, has been
introduced in this country. According to the original patents of G. J.
Atkins, the process consisted in bringing small or powdered carbide into
mechanical contact with some solid material containing water, the water
being either mixed with the solid reagent or attached to it as water of
crystallisation. Such reagents indeed were claimed as crude starch and
the like, the idea being to recover a by-product of pecuniary value. Now
the process seems to be known only in that particular form in which
granulated carbide is treated with crystallised sodium carbonate,
_i.e._, common washing soda. Assuming the carbide employed to be
chemically pure and the reaction between it and the water of
crystallisation contained in ordinary soda crystals to proceed
quantitatively, the production of acetylene by the dry process should be
represented by the following chemical equation:
5CaC_2 + Na_2CO_3.10H_2O = 5C_2H_2 + 5Ca(OH)_2 + Na_2CO_3.
On calculating out the molecular weights, it will be seen that 286 parts
of washing soda should suffice for the decomposition of 320 parts of pure
calcium carbide, or in round numbers 9 parts of soda should decompose 10
parts of carbide. In practice, however, it seems to be found that from 1
to 1.5 parts of soda are needed for every part of carbide.
The apparatus employed is a metal drum supported on a hollow horizontal
spindle, one end of which is closed and carries a winch handle, and the
other end of which serves to withdraw the gas generated in the plant. The
drum is divided into three compartments by means of two vertical
partitions so designed that when rotation proceeds in one particular
direction portions of the two reagents stored in one end compartment pass
into the centre compartment; whereas when rotation proceeds in the
opposite direction, the material in the centre compartment is merely
mixed together, partly by the revolution of the drum, partly with the
assistance of a stationary agitator slung loosely from the central
spindle. The other end compartment contains coke or sawdust or other dry
material through which the gas passes for the removal of lime or other
dust carried in suspension as it issues from the generating compartment.
The gas then passes through perforations into the central spindle, one
end of which is connected by a packed joint with a fixed pipe, which
leads to a seal or washer containing petroleum. Approached from a
theoretical standpoint, it will be seen that this method of generation
entirely sacrifices the advantages otherwise accruing from the use of
liquid water as a means for dissipating the heat of the chemical
reaction, but on the other hand, inasmuch as the substances are both
solid, the reaction presumably occurs more slowly than it would in the
presence of liquid water; and moreover the fact that the water employed
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