Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
to act upon the carbide is in the solid state and also more or less
combined with the rest of the sodium carbonate molecule, means that, per
unit of weight, the water decomposed must render latent a larger amount
of heat than it would were it liquid. Experiments made by one of the
authors of this book tend to show that the gas evolved from carbide by
the dry process contains rather less phosphorus than it might in other
conditions of generation, and as a fact gas made by the dry process is
ordinarily consumed without previous passage through any chemical
purifying agent. It is obvious, however, that the use of the churn
described above greatly increases the labour attached to the production
of the gas; while it is not clear that the yield per unit weight of
carbide decomposed should be as high as that obtained in wet generation.
The inventor has claimed that his by-product should be valuable and
saleable, apparently partly on the ground that it should contain caustic
soda. Evidence, however, that a reaction between the calcium oxide or
hydroxide and the sodium carbonate takes place in the prevailing
conditions is not yet forthcoming, and the probabilities are that such
decomposition would not occur unless the residue were largely diluted
with water. [Footnote: The oldest process employed for manufacturing
caustic soda consisted in mixing a solution of sodium carbonate with
quick or slaked lime, and it has been well established that the
causticisation of the soda will not proceed when the concentration of the
liquid is greater than that corresponding with a specific gravity of
about 1-10, _i.e._, when the liquid contains more than some 8 to 10
per cent, of sodium hydroxide.] Conversely there are some grounds for
believing that the dry residue is less useful than an ordinary wet
residue for horticultural purposes, and also for the production of
whitewash. From a financial standpoint, the dry process suffers owing to
the expense involved in the purchase of a second raw material, for which
but little compensation can be discovered unless it is proved that the
residue is intrinsically more valuable than common acetylene-lime and can
be sold or used advantageously by the ordinary owner of an installation.
The discarding of the chemical purifier at the present day is a move of
which the advantage may well be overrated.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account