Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Ammonia is objectionable in acetylene because it corrodes brass fittings
and pipes, and because it is partially converted (to what extent is
uncertain) into nitrous and nitric acids as it passes through the flame.
Sulphur is objectionable in acetylene because it is converted into
sulphurous and sulphuric anhydrides, or their respective acids, as it
passes through the flame. Phosphorus is objectionable because in similar
circumstances it produces phosphoric anhydride and phosphoric acid. Each
of these acids is harmful in an occupied room because they injure the
decorations, helping to rot book-bindings, [Footnote: It is only fair to
state that the destruction of leather bindings is commonly due to traces
of sulphuric acid remaining in the leather from the production employed
in preparing it, and is but seldom caused directly by the products of
combustion coming from gas or oil.] tarnishing "gold-leaf" ornaments, and
spoiling the colours of dyed fabrics. Each is harmful to the human
system, sulphuric and phosphoric anhydrides (SO_3, and P_4O_10) acting as
specific irritants to the lungs of persons predisposed to affections of
the bronchial organs. Phosphorus, however, has a further harmful action:
sulphuric anhydride is an invisible gas, but phosphoric anhydride is a
solid body, and is produced as an extremely fine, light, white voluminous
dust which causes a haze, more or less opaque, in the apartment.
[Footnote: Lewes suggests that ammonia in the gas burnt may assist in the
production of this haze, owing to the formation of solid ammonium salts
in the state of line dust.] Immediately it comes in contact with
atmospheric moisture phosphoric anhydride is converted into phosphoric
acid, but this also occurs at first as a solid substance. The solidity
and visibility of the phosphoric anhydride and acid are beneficial in
preventing highly impure acetylene being unwittingly burnt in a room;
but, on the other hand, being merely solids in suspension in the air, the
combustion products of phosphorus are not so easily carried away from the
room by the means provided for ventilation as are the products of the
combustion of sulphur. Phosphoric anhydride is also partly deposited in
the solid state at the burner orifices, perhaps actually corroding the
steatite jets, and always assisting in the deposition of carbon from any
polymerised hydrocarbons in the acetylene; thus helping the carbon to
block up or distort those orifices. Whenever the acetylene is to be burnt
on the incandescent system under a mantle of the Welsbach or other type,
phosphorus, and possibly sulphur, become additionally objectionable, and
rigorous extraction is necessary. As is well known, the mantle is
composed of the oxides of certain "rare earths" which owe their practical
value to the fact that they are non-volatile at the temperature of the
gas-flame. When a gas containing phosphorus is burnt beneath such a
mantle, the phosphoric anhydride attacks those oxides, partially
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