Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
that the other silicides in commercial calcium carbide also behave in
this manner it is plain that hydrogen silicide cannot occur in crude
acetylene unless the gas is supposed to be hurried out of the generator
before the alkaline water therein has had time to decompose any traces of
the hydrogen silicide which is produced in the favouring conditions of
high temperature sometimes prevailing. Mauricheau-Beaupré has failed to
find silica in the products of combustion of acetylene from carbide of
varying degrees of purity. He found, however, that a mixture of strong
nitric and hydrochloric acids (_aqua regia_), if contaminated with
traces of phosphoric acid, dissolved silica from the glass of laboratory
vessels. Consequently, since phosphoric acid results from the phosphine
in crude acetylene when the gas is passed through aqua regia, silica may
be found on subsequently evaporating the latter. But this, silica, he
found, was derived from the glass and not through the oxidation of
silicon compounds in the acetylene. It is possible that some of the
earlier observers of the occurrence of silicon compounds in crude
acetylene may have been misled by the solution of silica from the glass
vessels used in their investigations. The improbability of recognisable
quantities of silicon compounds occurring in acetylene in any ordinary
conditions of generation is demonstrated by a recent study by Fraenkel of
the composition of the deposit produced on reflectors exposed to the
products of combustion of a sample of acetylene which afforded a haze
when burnt. The deposit contained 51.07 per cent. of phosphoric acid, but
no silica. The gas itself contained from 0.0672 to 0.0837 per cent. by
volume of phosphine.
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